1
JEE Advanced 2015 Paper 2 Offline
MCQ (More than One Correct Answer)
+4
-2
Paragraph
When 100 mL of 1.0 M HCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
Enthalpy of dissociation (in kJ/mol) of acetic acid obtained from the Expt. 2 is
A
1.0
B
10.0
C
24.5
D
51.4
2
JEE Advanced 2015 Paper 2 Offline
MCQ (More than One Correct Answer)
+4
-2
Paragraph
When 100 mL of 1.0 M KCl was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7o C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is constant (-57.0 kJ/mol), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2) 100 mL of 2.0 M acetic acid (Ka = 2.0 $$\times$$ 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6o C was measured. (Consider heat capacity of all solutions as 4.2 J/gK and density of all solutions as 1.0 g m/L)
Question
The pH of the solution after Expt. 2 is
A
2.8
B
4.7
C
5.0
D
7.0
3
JEE Advanced 2013 Paper 2 Offline
MCQ (More than One Correct Answer)
+3
-0.75
The Ksp of Ag2CrO4 is 1.1 $$\times$$ 10-12 at 298 K. The solubility (in mol/L) of Ag2CrO4 in a 0.1 M AgNO3 solution is
A
1.1 $$\times$$ 10-11
B
1.1 $$\times$$ 10-10
C
1.1 $$\times$$ 10-12
D
1.1 $$\times$$ 10-9
4
JEE Advanced 2013 Paper 2 Offline
MCQ (More than One Correct Answer)
+3
-0.75
The thermal dissociation equilibrium of CaCO3(s) is studied under different conditions

CaCO3(s) $$\leftrightharpoons$$ CaO(s) + CO2(g).

For this equilibrium, the correct statement(s) is (are)
A
$$\Delta H$$ is dependent on T
B
K is independent of the initial amount of CaCO3
C
K is dependent on the pressure of CO2 at a given T
D
$$\Delta H$$ is independent of catalyst, if any
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