1
JEE Advanced 2016 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-0
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Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following equations:
X2 (g) $$\leftrightharpoons$$ 2X (g)
The standard reaction Gibbs energy, $$\Delta _rG^o$$, of this reaction is positive. At the start of the reaction, there is one mole of X2 and no X. As the reaction proceeds, the number of moles of X formed is given by $$\beta$$. Thus, $$\beta _{equilibrium}$$ is the number of moles of X formed at equilibrium. The reaction is carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally. (Given R = 0.083 L bar K-1 mol-1)
Question
The INCORRECT statement among the following for this reaction, is
A
Decrease in the total pressure will result in formation of more moles of gaseous X
B
At the start of the reaction, dissociation of gaseous X2 takes place spontaneously
C
$${{\beta _{equilibrium}}}$$ = 0.7
D
Kc < 1
2
JEE Advanced 2016 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-0
Change Language
Paragraph
Thermal decomposition of gaseous X2 to gaseous X at 298 K takes place according to the following equations:
X2 (g) $$\leftrightharpoons$$ 2X (g)
The standard reaction Gibbs energy, $$\Delta _rG^o$$, of this reaction is positive. At the start of the reaction, there is one mole of X2 and no X. As the reaction proceeds, the number of moles of X formed is given by $$\beta$$. Thus, $$\beta _{equilibrium}$$ is the number of moles of X formed at equilibrium. The reaction is carried out at a constant total pressure of 2 bar. Consider the gases to behave ideally. (Given R = 0.083 L bar K-1 mol-1)
Question
The equilibrium constant Kp for this reaction at 298 K, in terms of $$\beta _{equilibrium}$$, is
A
$${{8\beta _{equilibrium}^2} \over {2 - {\beta _{equilibrium}}}}$$
B
$${{8\beta _{equilibrium}^2} \over {4 - {\beta _{equilibrium}^2}}}$$
C
$${{4\beta _{equilibrium}^2} \over {2 - {\beta _{equilibrium}}}}$$
D
$${{4\beta _{equilibrium}^2} \over {4 - {\beta _{equilibrium}^2}}}$$
3
IIT-JEE 2008 Paper 1 Offline
MCQ (Single Correct Answer)
+3
-1

Statement 1 : For every chemical reaction at equilibrium, standard Gibbs energy of reaction is zero.

and

Statement 2 : At constant temperature and pressure, chemical reactions are spontaneous in the direction of decreasing Gibbs energy.

A
Statement 1 is True, Statement 2 is True; Statement 2 is correct explanation for Statement 1.
B
Statement 1 is True, Statement 2 is True; Statement 2 is NOT correct explanation for Statement 1.
C
Statement 1 is True, Statement 2 is False.
D
Statement 1 is False, Statement 2 is True.
4
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

$$ \begin{aligned} & \mathrm{Ag}^{+}+\mathrm{NH}_3 \quad\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)\right]^{+} \\ & k_1=3.5 \times 10^{-3} \\ & {\left[\mathrm{Ag}\left(\mathrm{NH}_3\right]^{+}+\mathrm{NH}_3 \quad\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}\right.} \end{aligned} $$

$k_2=1.7 \times 10^{-3}$, then the formation constant of $\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}$ is :

A

$6.08 \times 10^{-6}$

B

$6.08 \times 10^6$

C

$6.08 \times 10^{-9}$

D

None of these

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