1
IIT-JEE 1992
Subjective
+4
-0
At room temperature the following reacton is procedd nearly to completion:

2NO + O2 $$\to$$ 2NO2 $$\to$$ N2O4

The dimer, N2O4, solidifies at 262 K. A 250 ml flask and a 100 ml flask are separated by a stop-cock. At 300 K, the nitric oxide in the larger flask exerts a pressure of 1.053 atm. and the smaller one contains oxygen at 0.789 atm. The gases are mixed by the opening stopcock and after the end of raction the flasks are cooled at 220K. Neglecting the vapour pressure of the dimer, find out the pressure and composition of the gas remaining at 220 K. (Assume the gases to behave ideally)
2
IIT-JEE 1991
Subjective
+2
-0
Calculate the volume occupied by 5.0 g of acetylene gas at 50oC and 740 mm pressure.
3
IIT-JEE 1985
Subjective
+2
-0
Calculate the root mean square velocity of ozone kept in a closes vessel at 20oC and 82 cm mercury pressure.
4
IIT-JEE 1982
Subjective
+4
-0
At room temparature, ammonia gas at 1 atm pressure and hydrogen chloride gas at P atm pressure are allowed to effuse through identical pin holes from opposite ends of a glass tube of one metre length and of uniform cross-section. Ammonium chloride is first formed at a distance of 60 cm from the end through which HCL gas is sent in. What is the value of P?
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