The entropy versus temperature plot for phases $\alpha$ and $\beta$ at 1 bar pressure is given. $S_{\mathrm{T}}$ and $S_0$ are entropies of the phases at temperatures $\mathrm{T}$ and $0 \mathrm{~K}$, respectively.


The transition temperature for $\alpha$ to $\beta$ phase change is $600 \mathrm{~K}$ and $C_{\mathrm{p}, \beta}-C_{\mathrm{p}, \alpha}=1 \mathrm{~J} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$. Assume $\left(C_{\mathrm{p}, \beta}-C_{\mathrm{p}, \alpha}\right)$ is independent of temperature in the range of 200 to $700 \mathrm{~K} . C_{\mathrm{p}, \alpha}$ and $C_{\mathrm{p}, \beta}$ are heat capacities of $\alpha$ and $\beta$ phases, respectively.

$$ \text { The value of enthalpy change, } \mathrm{H}_\beta-\mathrm{H}_\alpha \text { (in } \mathrm{J} \mathrm{mol}^{-1} \text { ), at } 300 \mathrm{~K} \text { is } $$ ________.

A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction with an excess of $\mathrm{Sn} / \mathrm{HCl}$ gives a major product, which on treatment with an excess of $\mathrm{NaNO}_2 / \mathrm{HCl}$ at $0^{\circ} \mathrm{C}$ provides $\mathbf{P}$ as the product. $\mathbf{P}$, upon treatment with excess of $\mathrm{H}_2 \mathrm{O}$ at room temperature, gives the product $\mathbf{Q}$. Bromination of $\mathbf{Q}$ in aqueous medium furnishes the product $\mathbf{R}$. The compound $\mathbf{P}$ upon treatment with an excess of phenol under basic conditions gives the product $\mathbf{S}$.

The molar mass difference between compounds $\mathbf{Q}$ and $\mathbf{R}$ is $474 \mathrm{~g} \mathrm{~mol}^{-1}$ and between compounds $\mathbf{P}$ and $\mathbf{S}$ is $172.5 \mathrm{~g} \mathrm{~mol}^{-1}$.

The number of heteroatoms present in one molecule of $\mathbf{R}$ is _________.

[Use : Molar mass (in $\left.\mathrm{g} \mathrm{mol}^{-1}\right)$ : $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]

A trinitro compound, 1,3,5-tris-(4-nitrophenyl)benzene, on complete reaction with an excess of $\mathrm{Sn} / \mathrm{HCl}$ gives a major product, which on treatment with an excess of $\mathrm{NaNO}_2 / \mathrm{HCl}$ at $0^{\circ} \mathrm{C}$ provides $\mathbf{P}$ as the product. $\mathbf{P}$, upon treatment with excess of $\mathrm{H}_2 \mathrm{O}$ at room temperature, gives the product $\mathbf{Q}$. Bromination of $\mathbf{Q}$ in aqueous medium furnishes the product $\mathbf{R}$. The compound $\mathbf{P}$ upon treatment with an excess of phenol under basic conditions gives the product $\mathbf{S}$.

The molar mass difference between compounds $\mathbf{Q}$ and $\mathbf{R}$ is $474 \mathrm{~g} \mathrm{~mol}^{-1}$ and between compounds $\mathbf{P}$ and $\mathbf{S}$ is $172.5 \mathrm{~g} \mathrm{~mol}^{-1}$.

The total number of carbon atoms and heteroatoms present in one molecule of $\mathbf{S}$ is _________.

[Use : Molar mass (in $\mathrm{g} \mathrm{mol}^{-1}$ ): $\mathrm{H}=1, \mathrm{C}=12, \mathrm{~N}=14, \mathrm{O}=16, \mathrm{Br}=80, \mathrm{Cl}=35.5$
Atoms other than $\mathrm{C}$ and $\mathrm{H}$ are considered as heteroatoms]

Let $f:[1, \infty) \rightarrow \mathbb{R}$ be a differentiable function such that $f(1)=\frac{1}{3}$ and $3 \int\limits_1^x f(t) d t=x f(x)-\frac{x^3}{3}, x \in[1, \infty)$. Let $e$ denote the base of the natural logarithm. Then the value of $f(e)$ is :