1
IIT-JEE 2012 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-0.75
For a dilute solution containing 2.5 g of a non-volatile non-electrolyte solute in 100 g of water. the elevation in boiling point at 1 atm pressure is 2oC. Assuming concentration of solute is much lower than the concentration of solvent, the vapour pressure (mm of Hg) of the solution is (take Kb = 0.76 K Kg mol-1)
A
724
B
780
C
736
D
718
2
IIT-JEE 2012 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

The major product H of the given reaction sequence is

$$C{H_3} - C{H_2} - CO - C{H_3}\buildrel {\overline C N} \over \longrightarrow G\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{Heat}^{95\% \,{H_2}S{O_4}}} H$$

A
IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 24 English Option 1
B
IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 24 English Option 2
C
IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 24 English Option 3
D
IIT-JEE 2012 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 24 English Option 4
3
IIT-JEE 2012 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

$$NiC{l_2}{\{ P{({C_2}{H_5})_2}({C_6}{H_5})\} _2}$$ exhibits temperature-dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometries of Ni2+ in the paramagnetic and diamagnetic states are, respectively,

A
tetrahedral and tetrahedral.
B
square planar and square planar.
C
tetrahedral and square planar.
D
square planar and tetrahedral.
4
IIT-JEE 2012 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

The reaction of white phosphorous with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type; the oxidation states of phosphorus in phosphine and the other product are, respectively,

A
redox reaction; $$-$$3 and $$-$$5
B
redox reaction; +3 and +5
C
disproportionation reaction; $$-$$3 and +1
D
disproportionation reaction; $$-$$3 and +3
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