Solubility product constants (K$$_{sp}$$) of salts of types MX, MX$$_2$$ and M$$_3$$X at temperature T are 4.0 $$\times$$ 10$$^{-8}$$, 3.2 $$\times$$ 10$$^{-14}$$ and 2.7 $$\times$$ 10$$^{-15}$$, respectively. Solubilities (mol dm$$^{-3}$$) of the salts at temperature 'T' are in the order:
Statement 1 : Aniline on reaction with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol gives a dark blue coloured precipitate.
Statement 2 : The colour of the compound formed in the reaction of aniline with NaNO$$_2$$/HCl at 0$$^\circ$$C followed by coupling with $$\beta$$-naphthol is due to the extended conjugation.
Statement 1 : [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ is paramagnetic.
Statement 2 : The Fe in [Fe(H$$_2$$O)$$_5$$NO]SO$$_4$$ has three unpaired electrons.
Statement 1 : The geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] are optically inactive.
Statement 2 : Both geometrical isomers of the complex [M(NH$$_3$$)$$_4$$Cl$$_2$$] possess axis of symmetry.