1
IIT-JEE 2000
Subjective
+2
-0
The following electrochemical cell has been set up.
Pt(1) | Fe3+, Fe2+ (a = 1) | Ce4+, Ce3+ (a=1) | Pt(2)
Eo (Fe3+, Fe2+) = 0.77 V; Eo (Ce4+, Ce3+) = 1.61 V
If an ammeter is connected between the two platinum electrodes, predict the direction of flow of current. Will the current increase or decrease with time?
2
IIT-JEE 2000
Subjective
+3
-0
A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the presence of a catalyst at the same rate, the temperature required is 400 K. Calculate the activation energy of the reaction if the catalyst lowers the activation barrier by 20 kJ mol-1.
3
IIT-JEE 2000
Subjective
+3
-0
In any triangle $$ABC,$$ prove that $$$\cot {A \over 2} + \cot {B \over 2} + \cot {C \over 2} = \cot {A \over 2}\cot {B \over 2}\cot {C \over 2}.$$$
4
IIT-JEE 2000
Subjective
+4
-0
If $$\alpha ,\,\beta $$ are the roots of $$a{x^2} + bx + c = 0$$, $$\,\left( {a \ne 0} \right)$$ and $$\alpha + \delta ,\,\,\beta + \delta $$ are the roots of $$A{x^2} + Bx + c = 0,$$ $$\left( {A \ne 0\,} \right)\,$$ for some contant $$\delta $$, then prove that $${{{b^2} - 4ac} \over {{a^2}}} = {{{B^2} - 4Ac} \over {{A^2}}}$$.
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