The wave function, $${\psi _{n,1,{m_1}}}$$ is a mathematical function whose value depends upon spherical polar coordinates $$\left( {r,\theta ,\phi } \right)$$ of the electron and characterized by the quantum numbers $$n,1$$ and $${m_1}$$. Here $$r$$ is distance from nucleus, $$\theta $$ is colatitude and $$\phi $$ is azimuth. In the mathematical functions given in the table, $$Z$$ is atomic number and $${a_0}$$ is Bohr radius.

For the given orbital in Column 1, the only CORRECT combination for any hydrogen-like species is :

P is the probability of finding the 1s electron of hydrogen atom in a spherical shell of infinitesimal thickness, dr, at a distance r from the nucleus. The volume of this shell is $$4\pi r^2dr$$. The quantitative ketch of the dependence of P on r is

The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [$$\alpha_0$$ is Bohr radius]

The hydrogen like species Li²⁺ is in a spherically symmetric state S₁ with one radial node. Upon absorbing light the ion undergoes transition to a state S₂. The state S₂ has one radial node and its energy is equal to the ground state energy of the hydrogen atom.

The state S₁ is :