1
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J and K compound J upon reaction with KOH gives benzyl alcohol and a compound L, whereas K on reaction with KOH gives only M.

IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English Comprehension

The structure of compound I is :

A
IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English Option 1
B
IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English Option 2
C
IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English Option 3
D
IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 14 English Option 4
2
IIT-JEE 2008 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

A tertiary alcohol H upon acid catalysed dehydration gives a product I. Ozonolysis of I leads to compounds J and K compound J upon reaction with KOH gives benzyl alcohol and a compound L, whereas K on reaction with KOH gives only M.

IIT-JEE 2008 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 15 English Comprehension

The structures of compound J, K and L, respectively, are:

A
PhCOCH$$_3$$, PhCH$$_2$$COCH$$_3$$ and PHCH$$_2$$COO$$^-$$K$$^+$$.
B
PhCHO, PhCH$$_2$$CHO and PhCOO$$^-$$K$$^+$$
C
PhCOCH$$_3$$, PhCH$$_2$$CHO and CH$$_3$$COO$$^-$$K$$^+$$
D
PhCHO, PhCOCH$$_3$$ and PhCOO$$^-$$K$$^+$$
3
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Riemer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.

IIT-JEE 2007 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 12 English Comprehension

Which one of the following reagents is used in the above reaction?

A
aq. $$\mathrm{NaOH}+\mathrm{CH}_{3} \mathrm{Cl}$$
B
aq. $$\mathrm{NaOH}+\mathrm{CH}_{2} \mathrm{Cl}_{2}$$
C
aq. $$\mathrm{NaOH}+\mathrm{CHCl}_{3}$$
D
aq. $$\mathrm{NaOH}+\mathrm{CCl}_{4}$$
4
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1

Riemer-Tiemann reaction introduces an aldehyde group, on to the aromatic ring of phenol, ortho to the hydroxyl group. This reaction involves electrophilic aromatic substitution. This is a general method for the synthesis of substituted salicylaldehydes as depicted below.

IIT-JEE 2007 Paper 2 Offline Chemistry - Alcohols, Phenols and Ethers Question 11 English Comprehension

The electrophile in this reaction is :

A
$$:\mathrm{CHCl}$$
B
$${ }^{+} \mathrm{CHCl}_{2}$$
C
$$:\mathrm{CCl}_{2}$$
D
$$.\mathrm{CCl}_{3}$$

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