The reaction of Cl2 gas with cold-dilute and hot-concentrated NaOH in water give sodium salts of two (different) oxoacids of chlorine, P and Q, respectively. The Cl2 gas reacts with SO2 gas, in presence of charcoal, to give a product R. R reacts with white phosphorus to give a compound S. On hydrolysis, S gives an oxoacid of phosphorus, T.
R, S and T respectively, are
The unbalanced chemical reactions given in List I show missing reagent or condition (?) which are provided in List II. Match List I with List II and select the correct answer using the code given below the lists :
| List I | List II | ||
|---|---|---|---|
| P. | $$Pb{O_2} + {H_2}S{O_4}\buildrel ? \over \longrightarrow PbS{O_4} + {O_2} + Other\,products$$ |
1. | NO |
| Q. | $$N{a_2}{S_2}{O_3} + {H_2}O\buildrel ? \over \longrightarrow NaHS{O_4} + Other\,products$$ |
2. | $${I_2}$$ |
| R. | $${N_2}{H_4}\buildrel ? \over \longrightarrow {N_2} + Other\,products$$ |
3. | Warm |
| S. | $$Xe{F_2}\buildrel ? \over \longrightarrow Xe + Other\,products$$ |
4. | $$C{l_2}$$ |
Concentrated nitric acid, upon long standing, turns yellow-brown due to the formation of
The reaction of white phosphorous with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type; the oxidation states of phosphorus in phosphine and the other product are, respectively,