Match the orbital overlap figures shown in List I with the description given in List II and select the correct answer using the code given below the lists.

Different possible thermal decomposition pathways for peroxyesters are shown below. Match each pathway from List I with an appropriate structure from List II and select the correct answer using the code given below the lists.

Match the four starting materials (P, Q, R, S) given in List I with the corresponding reaction schemes (I, II, III, IV) provided in List II and select the correct answer using the code given below the lists.

Let $${z_k}$$ = $$\cos \left( {{{2k\pi } \over {10}}} \right) + i\,\,\sin \left( {{{2k\pi } \over {10}}} \right);\,k = 1,2....,9$$

List-I

P. For each $${z_k}$$ = there exits as $${z_j}$$ such that $${z_k}$$.$${z_j}$$ = 1
Q. There exists a $$k \in \left\{ {1,2,....,9} \right\}$$ such that $${z_1}.z = {z_k}$$ has no solution z in the set of complex numbers
R. $${{\left| {1 - {z_1}} \right|\,\left| {1 - {z_2}} \right|\,....\left| {1 - {z_9}} \right|} \over {10}}$$ equals
S. $$1 - \sum\limits_{k = 1}^9 {\cos \left( {{{2k\pi } \over {10}}} \right)} $$ equals

List-II

1. True
2. False
3. 1
4. 2