An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of M2 on reaction with reagent S gives white precipitate which dissolves in excess of S. The reactions are summarised in the scheme given below:
SCHEME:
An aqueous solution of metal ion M1 reacts separately with reagents Q and R in excess to give tetrahedral and square planar complexes, respectively. An aqueous solution of another metal ion M2 always forms tetrahedral complexes with these reagents. Aqueous solution of M2 on reaction with reagent S gives white precipitate which dissolves in excess of S. The reactions are summarised in the scheme given below:
SCHEME:
Reagent S is
Match each coordination compound in List I with an appropriate pair of characteristics from List II and select the correct answer using the code given below the lists.
{en = H2NCH2CH2NH2; atomic numbers : Ti = 22, Cr = 24; Co = 27; Pt = 78}
| List I | List II | ||
|---|---|---|---|
| P. | $$[Cr{(N{H_3})_3}C{l_2}]Cl$$ |
1. | Paramagnetic and exhibits ionisation isomerism. |
| Q. | $$[Ti{({H_2}O)_5}Cl]{(N{O_3})_2}$$ |
2. | Diamagnetic and exhibits cis-trans isomerism. |
| R. | $$[Pt(en)(N{H_3})Cl]N{O_3}$$ |
3. | Paramagnetic and exhibits cis-trans isomerism. |
| S. | $$[Co{(N{H_3})_4}{(N{O_3})_2}]N{O_3}$$ |
4. | Diamagnetic and exhibits ionisation isomerism. |
Match the orbital overlap figures shown in List I with the description given in List II and select the correct answer using the code given below the lists.
