1
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+4
-0

Match the reactions in Column I with nature of the reactions/type of the products in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) $$\mathrm{O_2^ - \to {O_2} + O_2^{2 - }}$$ (P) redox reaction
(B) $$\mathrm{CrO_4^{2 - } + {H^ + }}$$ (Q) one of the products has trigonal planar structure
(C) $$\mathrm{MnO_4^ - + NO_2^ - + {H^ + } \to}$$ (R) dimeric bridged tetrahedral metal ion
(D) $$\mathrm{NO_3^ - + {H_2}S{O_4} + F{e^{2 + }} \to }$$ (S) disproportionation

A
$$\mathrm{A-(p,s);B-(r);C-(p,q);D-(p)}$$
B
$$\mathrm{A-(p);B-(r);C-(p);D-(p)}$$
C
$$\mathrm{A-(p,s);B-(r);C-(p);D-(p, q)}$$
D
$$\mathrm{A-(p);B-(r, s);C-(p,q);D-(p)}$$
2
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+4
-0

Match the compounds/ions in Column I with their properties/reactions in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) $$\mathrm{C_6H_5CHO}$$ (P) gives precipitate with 2, 4-dinitrophenylhydrazine
(B) $$\mathrm{CH_3C\equiv CH}$$ (Q) gives precipitate with $$\mathrm{AgNO_3}$$
(C) $$\mathrm{CN^-}$$ (R) is a nucleophile
(D) $$\mathrm{I^-}$$ (S) is involved in cyanohydrin formation

A
$$\mathrm{A-(p,s);B-(q);C-(r,s);D-(q)}$$
B
$$\mathrm{A-(p,s);B-(q);C-(q,r,s);D-(q,r)}$$
C
$$\mathrm{A-(s);B-(q);C-(q,r,s);D-(q)}$$
D
$$\mathrm{A-(p);B-(q);C-(s);D-(r)}$$
3
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+4
-0

Match the crystal system/unit cells mentioned in Column I with their characteristic features mentioned in Column II. Indicate your answer by darkening the appropriate bubbles of the 4 $$\times$$ 4 matrix given in the ORS.

Column I Column II
(A) Simple cubic and face-centred cubic (P) have these cell parameters $$a=b=c$$ and $$\alpha=\beta=\gamma$$
(B) cubic and rhombohedral (Q) are two crystal systems
(C) cubic and tetragonal (R) have only two crystallographic of 90$$^\circ$$
(D) hexagonal and monoclinic (S) belong to same crystal system

A
$$\mathrm{A-(s);B-(q);C-(q);(d)-(q,r)}$$
B
$$\mathrm{A-(p,s);B-(p);C-(q);(d)-(r)}$$
C
$$\mathrm{A-(p,s);B-(p,q);C-(q);(d)-(q,r)}$$
D
$$\mathrm{A-(s);B-(q);C-(q);(d)-(q)}$$
4
IIT-JEE 2007 Paper 2 Offline
MCQ (Single Correct Answer)
+3
-1
Let $${E^c}$$ denote the complement of an event $$E.$$ Let $$E, F, G$$ be pairwise independent events with $$P\left( G \right) > 0$$ and $$P\left( {E \cap F \cap G} \right) = 0.$$ Then $$P\left( {{E^c} \cap {F^c}|G} \right)$$ equals
A
$$P\left( {{E^c}} \right) + P\left( {{F^c}} \right)$$
B
$$P\left( {{E^c}} \right) - P\left( {{F^c}} \right)$$
C
$$P\left( {{E^c}} \right) - P\left( F \right)$$
D
$$P\left( E \right) - P\left( {{F^c}} \right)$$

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