Decrease in atomic number is observed during

The energy of an electron in the first Bohr orbit of H atom is -13.6 eV. The possible energy value(s) of the excited state(s) for electrons in Bohr orbits of hydrogen is (are)

The orbital diagram in which the Aufbau principle is violated is

ASSERTION:
Nuclide $${}_{13}^{30}Al$$ is less stable than $${}_{20}^{40}Ca$$

REASON:
Nuclides having odd number of protons and neutrons are generally unstable.