The freezing point of equimolal aqueous solutions will be highest for

The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile non-electrolyte solid weighing 2.175 g is added to 39.0 g of benzene. The vapour pressure of the solution is 600 mm Hg. What is the molecular weight of the solid substance?

The equation $$\left( {\cos p - 1} \right){x^2} + \left( {\cos p} \right)x + \sin p = 0\,$$ In the variable x, has real roots. Then p can take any value in the interval