The freezing point of equimolal aqueous solutions will be highest for

The vapour pressure of pure benzene at a certain temperature is 640 mm Hg. A non-volatile non-electrolyte solid weighing 2.175 g is added to 39.0 g of benzene. The vapour pressure of the solution is 600 mm Hg. What is the molecular weight of the solid substance?

Prove that for any positive integer $$k$$,
$${{\sin 2kx} \over {\sin x}} = 2\left[ {\cos x + \cos 3x + ......... + \cos \left( {2k - 1} \right)x} \right]$$
Hence prove that $$\int\limits_0^{\pi /2} {\sin 2kx\,\cot \,x\,dx = {\pi \over 2}} $$