The oxidation number of phosphorus in Ba(H₂PO₂) is :

A mixture of H₂C₂O₄ (oxalic acid) and NaHC₂O₄ weighing 2.02 g was dissolved in water and solution made upto one litre. Ten millilitres of the solution required 3.0 ml. of 0.1 N sodium hydroxide solution for complete neutralization. In another experiment, 10.0 ml. of the same solution, in hot dilute sulphuric acid medium. require 4.0 ml. of 0.1 N potassium permanganate solution for complete reaction. Calculate the amount of H₂C₂O₄ and NaHC₂O₄ in the mixture.

A solid mixture (5.0 g) consisting of lead nitrate and sodium nitrate was headed below 600^oC until the weight of the residue was constant. If the loss in weight 28.0 percent, find the amount of lead nitrate and sodium nitrate in the mixture.

According to Bohr's theory, the electronic energy of hydrogen atom in the n^th Bohr's orbit is given by $${E_n} = {{ - 21.6 \times {{10}^{ - 19}}} \over {{n^2}}}J$$. Calculate the longest wavelength of light (in Å) that will be needed to remove an electron from the third Bohr orbit of the He⁺ ion.