Consider the following reaction sequence in which $\mathbf{J}, \mathbf{K}, \mathbf{L}$ and $\mathbf{M}$ are the major products.

Given:

Atomic mass (in amu) : $\mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{~S}: 32, \mathrm{Br}: 80, \mathrm{Ba}: 137$

The volume of 1 M aqueous $\mathrm{H}_2 \mathrm{SO}_4$ required to completely neutralize the ammonia evolved from 5.72 g of $\mathbf{L}$ in Kjeldahl's method of nitrogen estimation is $\_\_\_\_$ mL .

Consider the following reaction sequence in which $\mathbf{J}, \mathbf{K}, \mathbf{L}$ and $\mathbf{M}$ are the major products.

Given :

Atomic mass (in amu) : $\mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{~S}: 32, \mathrm{Br}: 80, \mathrm{Ba}: 137$

In sulphur estimation by Carius method, the amount of $\mathrm{BaSO}_4$ formed from 3.79 g of $\mathbf{M}$ is $\_\_\_\_$ g.

Let $ \vec{a}, \vec{b} $ be two vectors, and let P, Q and R be the points with position vectors $ \vec{a}, \vec{b} $ and $ \vec{a} + \vec{b} $, respectively, with respect to the origin O. If $ |\vec{a} + \vec{b}| = \sqrt{21} $, $ |\vec{a} - \vec{b}| = 3 $, and $ \vec{a} $ and $ (\vec{a} - \vec{b}) $ are perpendicular to each other, then the area of the triangle OPR is :

Let T be the tangent to the parabola $y^2 = 16x$ at the point $(64, 32)$. Let L be the tangent to the same parabola at another point $(x_1, y_1)$ on the parabola. If L and T are perpendicular to each other, then the distance between the point $(x_1, y_1)$ and the focus of the parabola, is :