Consider that the coordinating atoms of the ligands in cis- $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$ and mer- $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]$ octahedral complexes are at the vertices of an octahedron. The sum of total number of the triangular faces in both the complexes having one N atom and two Cl atoms at their corners is $\_\_\_\_$ .

In the following reaction sequence, major products $\mathbf{X}$ and $\mathbf{Y}$ are acyclic monomers.

500 mol of $\mathbf{X}$ completely reacts with 500 mol of $\mathbf{Y}$ to give 1 mol of a single biodegradable acyclic copolymer $\mathbf{Z}$ as the only product. The amount of $\mathbf{Z}$ formed in grams is $\_\_\_\_$ .

Given :

Atomic mass (in amu): $\mathrm{H}: 1, \mathrm{C}: 12, \mathrm{~N}: 14, \mathrm{O}: 16, \mathrm{Br}: 80$

Two volatile liquids $\mathbf{A}$ and $\mathbf{B}$ form an ideal solution. Consider a 5 molal solution of $\mathbf{B}$ in $\mathbf{A}$ inside a closed container having a total vapour pressure of 100 mm Hg at 300 K . The vapour pressure of pure $\mathbf{A}$ at 300 K is 105 mm Hg . Assume that $\mathbf{A}$ and $\mathbf{B}$ behave as ideal gases in the vapour phase.

Given :

The gas constant $R=0.08 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$

Molar mass of $\mathbf{A}$ is $50 \mathrm{~g} \mathrm{~mol}^{-1}$

Molar mass of $\mathbf{B}$ is $57 \mathrm{~g} \mathrm{~mol}^{-1}$

Density of liquid $\mathbf{B}$ at 300 K is $0.5 \mathrm{~g} / \mathrm{mL}$

$1 \mathrm{~atm}=760 \mathrm{~mm} \mathrm{Hg}$

At 300 K , the ratio of the molar volume of pure $\mathbf{B}$ in vapour phase to its molar volume in liquid phase is $\_\_\_\_$ .

Two volatile liquids $\mathbf{A}$ and $\mathbf{B}$ form an ideal solution. Consider a 5 molal solution of $\mathbf{B}$ in $\mathbf{A}$ inside a closed container having a total vapour pressure of 100 mm Hg at 300 K . The vapour pressure of pure $\mathbf{A}$ at 300 K is 105 mm Hg . Assume that $\mathbf{A}$ and $\mathbf{B}$ behave as ideal gases in the vapour phase.

Given :

The gas constant $R=0.08 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$

Molar mass of $\mathbf{A}$ is $50 \mathrm{~g} \mathrm{~mol}^{-1}$

Molar mass of $\mathbf{B}$ is $57 \mathrm{~g} \mathrm{~mol}^{-1}$

Density of liquid $\mathbf{B}$ at 300 K is $0.5 \mathrm{~g} / \mathrm{mL}$

$1 \mathrm{~atm}=760 \mathrm{~mm} \mathrm{Hg}$

The mole fraction of $\mathbf{B}$ in vapour phase which is in equilibrium with this solution is $\_\_\_\_$ .