When 20 g of naphthoic acid (C$$_{11}$$H$$_{8}$$O$$_{2}$$) is dissolved in 50 g of benzene in 50 g of benzene (K$$_f$$ = 1.72 K kg mol$$^{-1}$$), a freezing point depression of 2 K is observed. The van't Hoff factor (i) is :

The value of log$$_{10}$$ K for a reaction $A \rightleftharpoons B$ is

(Given : $${\Delta _r}H{^\circ _{298\,K}} = - 54.07$$ kJ mol$$^{-1}$$, $${\Delta _r}S{^\circ _{298\,K}} = 10$$ J K$$^{-1}$$ mol$$^{-1}$$ and R = 8.314 J K$$^{-1}$$ mol$$^{-1}$$; 2.303 $$\times$$ 8.314 $$\times$$ 298 = 5705)

Statement 1 : Boron always forms covalent bond.

Statement 2 : The small size of B$$^{3+}$$ favours formation of covalent bond.

Statement 1 : In water, orthoboric acid behaves as a weak monobasic acid.

Statement 2 : In water, orthoboric acid acts as a proton donor.