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1
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

$\mathrm{CuSO}_4$ decolourises on addition of KCN , the product is

A

$\left[\mathrm{Cu}(\mathrm{CN})_4\right]^{2-}$

B

$\mathrm{Cu}^{2+}$ get reduced to form $\left[\mathrm{Cu}(\mathrm{CN})_4\right]^{3-}$

C

$\mathrm{Cu}(\mathrm{CN})_2$

D

CuCN

2
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

The direct conversion of A to B is difficult; hence, it is carried out by the following shown path:IIT-JEE 2006 Chemistry - Thermodynamics Question 3 EnglishGiven,

$$ \begin{aligned} & \Delta \mathrm{S}_{(\mathrm{A} \rightarrow \mathrm{C})}=50 \text { e.u. } \\ & \Delta \mathrm{S}_{(\mathrm{C} \rightarrow \mathrm{D})}=30 \text { e.u. } \\ & \Delta \mathrm{S}_{(\mathrm{B} \rightarrow \mathrm{D})}=20 \text { e.u. } \end{aligned} $$

Where e.u. is entropy unit. Then $\Delta \mathrm{S}_{(\mathrm{A} \rightarrow \mathrm{B})}$ is :

A

+100 e.u.

B

+60 e.u.

C

-100 e.u.

D

-60 e.u.

3
IIT-JEE 2006
MCQ (Single Correct Answer)
+3
-1

$$ \mathrm{N}_2+3 \mathrm{H}_2 \to 2 \mathrm{NH}_3 $$

Which is the correct statement if $\mathrm{N}_2$ is added at equilibrium condition?

A

The equilibrium will shift to forward direction because according to second law of thermodynamics, the entropy must increase in the direction of spontaneous reaction.

B

The condition for equilibrium is $\mathrm{G}_{\mathrm{N}_2}+3 \mathrm{G}_{\mathrm{H}_2} \quad 2 \mathrm{G}_{\mathrm{NH}_3}$ where G is Gibbs free energy per mole of the gaseous species measured at that partial pressure. The condition of equilibrium is unaffected by the use of catalyst, which increases the rate of both the forward and backward reactions to the same extent.

C

The catalyst will increase the rate of forward reaction by and that of backward reaction by $\beta$.

D

Catalyst will not alter the rate of either of the reaction.

4
IIT-JEE 2006
MCQ (More than One Correct Answer)
+3
-1

If the bond length of CO bond in carbon monoxide is $1.128 \mathop {\rm{A}}\limits^{\rm{o}}$, then what is the value of CO bond length in $\mathrm{Fe}(\mathrm{CO})_5$?

A

$1.15 \mathop {\rm{A}}\limits^{\rm{o}}$

B

$1.128\mathop {\rm{A}}\limits^{\rm{o}}$

C

$1.72 \mathop {\rm{A}}\limits^{\rm{o}}$

D

$1.118\mathop {\rm{A}}\limits^{\rm{o}}$

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