A solution of 0.2 g of a compound containing Cu²⁺ and $$C_2O_4^{2-}$$ ions on titration with 0.02M $$KMnO_4$$ in presence of $$H_2SO_4$$ consumes 22.6 ml. of the oxidant. The resultant solution in neutralized with Na₂CO₃, acidified with dil. acetic acid and treated with excess KI. The liberated iodine requires 11.3 ml of 0.05M Na₂S₂O₃ solution for complete reduction.

Find out the molar ratio of Cu²⁺ to $$C_2O_4^{2-}$$ in the compound.Write down the balanced redox reactions involved in the above titrations.

Read the following statement and explanation and answer as per the options given below:

STATEMENT (S): In the titration of Na₂CO₃ with HCl using methyl orange indicator, the volume required at the equivalence point is twice that of the acid required using phenolphthalein indicator.

EXPLANATION (E): Two moles of HCl are required for the complete neutralization of one mole of Na₂CO₃

Arrange of the following in :
Increasing order of ionic size:
N^3-, Na⁺, F^-, O^2-, Mg²⁺

Arrange of the following in :
Increasing order of basic character
MgO, SrO, K₂O, NiO, Cs₂O