1
IIT-JEE 1991
Fill in the Blanks
+1
-0
The weight of $$1 \times 10^{22}$$ molecules of CuSO4.5H2O is ____.
2
IIT-JEE 1991
MCQ (Single Correct Answer)
+1
-0.25
The oxidation state of the most electronegative element in the products of the reaction. BaO2 with dil. H2SO4 are
A
0 and -1
B
-1 and -2
C
-2 and 0
D
-2 and -1
3
IIT-JEE 1991
Subjective
+4
-0
A 1.0 g sample of Fe2O3 solid of 55.2% purity is dissolved in acid and reduced by heating the solution with zinc dust. The resultant solution is cooled and made upto 100.0 ml. An aliquot of 25.0 ml of this solution requires 17.0 ml of 0.0167M solution of an oxidant for titration. Calculate the number of electrons taken by the oxidant in the reaction of the above titration.
4
IIT-JEE 1991
Subjective
+5
-0
A solution of 0.2 g of a compound containing Cu2+ and $$C_2O_4^{2-}$$ ions on titration with 0.02M $$KMnO_4$$ in presence of $$H_2SO_4$$ consumes 22.6 ml. of the oxidant. The resultant solution in neutralized with Na2CO3, acidified with dil. acetic acid and treated with excess KI. The liberated iodine requires 11.3 ml of 0.05M Na2S2O3 solution for complete reduction.

Find out the molar ratio of Cu2+ to $$C_2O_4^{2-}$$ in the compound.Write down the balanced redox reactions involved in the above titrations.
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