The standard reduction potential for Cu²⁺|Cu is +0.34 V. Calculate the reduction potential at pH = 14 for the above couple. K_sp of Cu(OH)₂ is 1.0 $$\times$$ 10^-19

The ionisation constant of $$NH_4^+$$ in water is 5.6 $$\times$$ 10^-10 at 25^oC. The rate constant for the reaction of $$NH_4^+$$ and $$OH^-$$ to form NH₃ and H₂O at 25^oC is 3.4 $$\times$$ 10¹⁰ L mol^-1s^-1. Calculate the rate constant for proton transfer from water to NH₃.

If for nonzero $$x$$, $$af(x)+$$ $$bf\left( {{1 \over x}} \right) = {1 \over x} - 5$$ where $$a \ne b,$$ then
$$\int_1^2 {f\left( x \right)dx} = .......$$

Determine the equation of the curve passing through the origin, in the form $$y=f(x),$$ which satisfies the differential equation $${{dy} \over {dx}} = \sin \left( {10x + 6y} \right).\,$$