1
IIT-JEE 1992
Subjective
+1
-0
Give reasons of the following:
Hydrogen peroxide acts as an oxidising as well as a reducing agent.
2
IIT-JEE 1992
Subjective
+4
-0
For the galvanic cell
Ag | AgCl(s), KCl (0.2M) || KBr (0.001M), AgBr(s) | Ag
Calculate the EMF generated and assign correct polarity to each electrode for a spontaneous process after taking into account the cell reaction at 25oC.
[Ksp(AgCl) = 2.8 $$times$$ 10-10; Ksp(AgBr) = 3.3 $$times$$ 10-13]
3
IIT-JEE 1992
Subjective
+3
-0
An aqueous solution of NaCl on electrolysis gives H2(g), Cl2(g) and NaOH according to the reaction:
2Cl- (aq) + 2H2O = 2OH- (aq) + H2 (g) + Cl2 (g)
A direct current of 25 amperes with a current efficiency of 62 % is passed through 20 litres of NaCl solution (20% by weight). Write down the reactions taking place at the anode and cathode. How long will it take to produce 1kg of Cl2? What will be the molarity of the solution with respect to hydroxide ion? (Assume no loss due to evaporation)
4
IIT-JEE 1992
Subjective
+6
-0
A lot contains $$50$$ defective and $$50$$ non defective bulbs. Two bulbs are drawn at random, one at a time, with replacement. The events $$A, B, C$$ are defined as
$$A=$$ (the first bulbs is defective)
$$B=$$ (the second bulbs is non-defective)
$$C=$$ (the two bulbs are both defective or both non defective)
Determine whether
(i) $$\,\,\,\,\,$$ $$A, B, C$$ are pairwise independent
(ii)$$\,\,\,\,\,$$ $$A, B, C$$ are independent
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