An ideal gas (0.5 mol), initially at 2 bar pressure, is compressed at a constant temperature of 600 K in two steps: first, against a constant external pressure of P bar (2 < P < 8), and then against constant external pressure of 8 bar. At each step, the compression is stopped only when the pressure of the gas becomes equal to the external pressure. The total work done on the gas in these steps is W. Considering all possible values of P (2 < P < 8) and taking the gas constant as R (in J K⁻¹ mol⁻¹), the minimum value of |W| (in J) is

For a reversible reaction $R \rightleftharpoons P$, at constant temperature, both the forward and the backward reactions are first order elementary reactions with rate constants $k_{{f}}$ and $k_{{b}}$, respectively. At time zero, the concentration of $R$ is $[R]_0$ and the concentration of $P$ is zero. At any given time, $[R]$ and $[P]$ are the concentrations of $R$ and $P$, respectively. If $k_{{b}} = 4k_{{f}}$, the correct graphical representation of the reaction is

The correct order of dipole moments for the given species is

Considering LiBH₄ reduces an ester group to the corresponding alcohol and does not reduce a carboxylic acid group, the correct statement about the major products P, Q, R and S is: