1
IIT-JEE 2004
Subjective
+2
-0
For the given reactions, A + B $$\to$$ Products, following data were obtained
[Ao] [Bo] Ro (mol L-1 s-1)
1 0.1 0.1 0.05
2 0.2 0.1 0.10
3 0.1 0.2 0.05
(a) Write the rate law expression
(b) Find the rate constant
2
IIT-JEE 2004
Subjective
+4
-0
Find the equilibrium constant for the reaction,
In2+ + Cu2+ $$\to$$ In3+ + Cu+ at 298 K
given
$$E_{C{u^{2 + }}/C{u^ + }}^o$$ = 0.15 V; $$E_{l{n^{2 + }}/l{n^ + }}^o$$ = -0.40 V; $$E_{l{n^{3 + }}/l{n^ + }}^o$$ = -0.42 V;
3
IIT-JEE 2004
Subjective
+2
-0
1.22 g of benzoic acid is dissolved in 100 g of acetone and 100 g of benzene separately. Boiling point of the solution in acetone increases by 0.17 oC, while that in the benzene increases by 0.13oC; Kb for acetone and benzene is 1.7 K kg mol-1 and 2.6 K kg mol-1. Find molecular weight of the benzoic acid in two cases and justify your answer.
4
IIT-JEE 2004
Subjective
+2
-0
A compound AB has rock salt type structure. The formula weight of AB is 6.023 Y amu, and the closest A - B distance is Y1/3 nm, where Y is an arbitrary number
(a) Find the density of the lattice
(b) If the density of lattice is found to be 20 kg m-3, then predict the type of defect
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