IIT-JEE 1983
Paper was held on
Mon, Apr 11, 1983 9:00 AM
Chemistry
1
Elements of the same mass number but of different atomic numbers are known as ____.
2
The density of a 3 M Sodium thiosulphate solution (Na2S2O3) is 1.25 g per ml. Calculate
(i) the percentage by weight of sodium thiosulphate,
(ii) the mole fraction of sodium thiosulphate and
(iii) the molalities of Na+ and $$S_2O_3^{-2}$$ ions
(i) the percentage by weight of sodium thiosulphate,
(ii) the mole fraction of sodium thiosulphate and
(iii) the molalities of Na+ and $$S_2O_3^{-2}$$ ions
3
Complete and balance the following equation:
$$Cr_2O_7^{2-}$$ + C2H4O $$\to$$ C2H4O2 + Cr3+
$$Cr_2O_7^{2-}$$ + C2H4O $$\to$$ C2H4O2 + Cr3+
4
The principal quantum number of an atom is related to the
5
3 g of a salt of molecular weight 30 is dissolved in 250 g of water. The molality if the solution is _____.
6
Any p-orbital can accommodate upto
7
Carbon tetrachloride has no net dipole moment because of
8
An organic compound CxH2yOy was burnt with twice the amount of oxygen needed for complete combustion of CO2 and H2O. The hot gases when cooled to 0oC and 1 atm pressure, measured 2.24 litres. The water collected during cooling weighed 0.9 g. The vapour pressure of pure water at 20oC is 17.5 mm Hg and is lowered by 0.104 mm when 50 g of the organic compound are dissolved in 1000 g of water. Give the molecular formula of the organic compound.
9
The absorption of hydrogen by palladium is commonly known as ______.
10
Heavy water is
11
Linear overlap of two atomic p-orbitals leads to a sigma bond.
12
The types of bonds present in CuSO4.5H2O are only
13
Which one among the following does not have the hydrogen bond?
14
Gamma rays are electromagnetic radiations of wavelengths of 10-6 to 10-5 cm
15
Complete and balance the following equations:
Cl2 + OH- $$\to$$ Cl- + ClO-
Cl2 + OH- $$\to$$ Cl- + ClO-
16
Complete and balance the following equation:
HNO3 + HCl $$\to$$ NO + Cl2
HNO3 + HCl $$\to$$ NO + Cl2
17
The energy of the electron in the 3d-orbital is less than that in the 4s-orbital in the hydrogen atom.
18
4.08 g of a mixture of BaO and an unknown carbonate MCO3 was heated strongly. The residue weighed 3.64 g. This was dissolved in 100 ml of 1 N HCl. The excess acid required 16 ml of 2.5 N NaOH solution for complete neutralization. Identify the metal M. (At wt. H = 1, C = 12, O = 16, Cl = 35.5, Ba = 138)
19
Complete and balance the following equation:
Ce3+ + $$S_2O_8^{-2} \to $$ $$SO_4^{-2}$$ + Ce4+
Ce3+ + $$S_2O_8^{-2} \to $$ $$SO_4^{-2}$$ + Ce4+
20
Complete and balance the following equation:
Zn + $$NO_3^- \to$$ Zn2+ + $$NH_4^+$$
Zn + $$NO_3^- \to$$ Zn2+ + $$NH_4^+$$
21
Rutherford's scattering experiment is related to the size of the
Mathematics
1
If $$X.A=0, X.B=0, X.C=0$$ for some non-zero vector $$X,$$ then $$\left[ {A\,B\,C} \right] = 0$$
2
A vector $$\overrightarrow A $$ has components $${A_1},{A_2},{A_3}$$ in a right -handed rectangular Cartesian coordinate system $$oxyz.$$ The coordinate system is rotated about the $$x$$-axis through an angle $${\pi \over 2}.$$ Find the components of $$A$$ in the new coordinate system in terms of $${A_1},{A_2},{A_3}.$$
3
The area of the triangle whose vertices are $$A(1, -1, 2), B(2, 1, -1), C(3, -1, 2)$$ is ..........
4
The unit vector perpendicular to the plane determined by $$P\left( {1, - 1,2} \right),\,Q\left( {2,0, - 1} \right)$$ and $$R\left( {0,2,1} \right)$$ is ...........
5
$$A, B, C$$ are events such that
$$P\left( A \right) = 0.3,P\left( B \right) = 0.4,P\left( C \right) = 0.8$$
$$P\left( {AB} \right) = 0.08,P\left( {AC} \right) = 0.28;\,\,P\left( {ABC} \right) = 0.09$$
$$P\left( A \right) = 0.3,P\left( B \right) = 0.4,P\left( C \right) = 0.8$$
$$P\left( {AB} \right) = 0.08,P\left( {AC} \right) = 0.28;\,\,P\left( {ABC} \right) = 0.09$$
If $$P\left( {A \cup B \cup C} \right) \ge 0.75,$$ then show that $$P$$ $$(BC)$$ lies in the interval $$0.23 \le x \le 0.48$$
6
The points with position vectors $$60i+3j,$$ $$40i-8j,$$ $$ai-52j$$ are collinear if
7
Cards are drawn one by one at random from a well - shuffled full pack of $$52$$ playing cards until $$2$$ aces are obtained for the first time. If $$N$$ is the number of cards required to be drawn, then show that $${P_r}\left\{ {N = n} \right\} = {{\left( {n - 1} \right)\left( {52 - n} \right)\left( {51 - n} \right)} \over {50 \times 49 \times 17 \times 13}}$$ where $$2 \le n \le 50$$
8
The volume of the parallelopiped whose sides are given by
$$\overrightarrow {OA} = 2i - 2j,\,\overrightarrow {OB} = i + j - k,\,\overrightarrow {OC} = 3i - k,$$ is
$$\overrightarrow {OA} = 2i - 2j,\,\overrightarrow {OB} = i + j - k,\,\overrightarrow {OC} = 3i - k,$$ is
9
If the letters of the word "Assassin" are written down at random in a row, the probability that no two S's occur together is $$1/35$$
10
Fifteen coupons are numbered $$1, 2 ........15,$$ respectively. Seven coupons are selected at random one at a time with replacement. The probability that the largest number appearing on a selected coupon is $$9,$$ is
11
Find the area bounded by the $$x$$-axis, part of the curve $$y = \left( {1 + {8 \over {{x^2}}}} \right)$$ and
the ordinates at $$x=2$$ and $$x=4$$. If the ordinate at $$x=a$$ divides the area into two equal parts, find $$a$$.
the ordinates at $$x=2$$ and $$x=4$$. If the ordinate at $$x=a$$ divides the area into two equal parts, find $$a$$.
12
If $$\left( {a + bx} \right){e^{y/x}} = x,$$ then prove that $${x^3}{{{d^2}y} \over {d{x^2}}} = {\left( {x{{dy} \over {dx}} - y} \right)^2}$$
13
Evaluate : $$\int\limits_0^{\pi /4} {{{\sin x + \cos x} \over {9 + 16\sin 2x}}dx} $$
14
The value of the integral $$\int\limits_0^{\pi /2} {{{\sqrt {\cot x} } \over {\sqrt {\cot x} + \sqrt {\tan x} }}dx} $$ is
15
Evaluate : $$\int {{{\left( {x - 1} \right){e^x}} \over {{{\left( {x + 1} \right)}^3}}}dx} $$
16
The normal to the curve $$\,x = a\left( {\cos \theta + \theta \sin \theta } \right)$$, $$y = a\left( {\sin \theta - \theta \cos \theta } \right)$$ at any point $$'\theta '$$ is such that
17
If $${\left( {1 + x} \right)^n} = {C_0} + {C_1}x + {C_2}{x^2} + ..... + {C_n}{x^n}$$ then show that the sum of the products of the $${C_i}s$$ taken two at a time, represented $$\sum\limits_{0 \le i < j \le n} {\sum {{C_i}{C_j}} } $$ is equal to $${2^{2n - 1}} - {{\left( {2n} \right)!} \over {2{{\left( {n!} \right)}^2}}}$$
18
The end $$A, B$$ of a straight line segment of constant length $$c$$ slide upon the fixed rectangular axes $$OX, OY$$ respectively. If the rectangle $$OAPB$$ be completed, then show that the locus of the foot of the perpendicular drawn from $$P$$ to $$AB$$ is $${x^{{2 \over 3}}} + {y^{{2 \over 3}}} = {c^{{2 \over 3}}}$$
19
The straight lines $$x + y = 0,\,3x + y - 4 = 0,\,x + 3y - 4 = 0$$ form a triangle which is
20
Find three numbers $$a,b,c$$ between $$2$$ and $$18$$ such that
(i) their sum is $$25$$
(ii) the numbers $$2,$$ $$a, b$$ are consecutive terms of an A.P. and
(iii) the numbers $$b,c,18$$ are consecutive terms of a G.P.
(i) their sum is $$25$$
(ii) the numbers $$2,$$ $$a, b$$ are consecutive terms of an A.P. and
(iii) the numbers $$b,c,18$$ are consecutive terms of a G.P.
21
The straight line $$5x + 4y = 0$$ passes through the point of intersection of the straight lines $$x + 2y - 10 = 0$$ and $$2x + y + 5 = 0.$$
22
The rational number, which equals the number $$2\overline {357} $$ with recurring decimal is
23
m men and n women are to be seated in a row so that no two women sit together. If $$m > n$$, then show that the number of ways in which they can be seated is $$\,{{m!(m + 1)!} \over {(m - n + 1)!}}$$
24
If $${\left( {1 + ax} \right)^n} = 1 + 8x + 24{x^2} + .....$$ then $$a=..........$$ and $$n =............$$
25
Use mathematical Induction to prove : If $$n$$ is any odd positive integer, then $$n\left( {{n^2} - 1} \right)$$ is divisible by 24.
26
The coefficient of $${x^4}$$ in $${\left( {{x \over 2} - {3 \over {{x^2}}}} \right)^{10}}$$ is
27
The vertices of a triangle are
$$\left[ {a{t_1}{t_2},\,\,a\left( {{t_1} + {t_2}} \right)} \right],\,\,\left[ {a{t_2}{t_3},a\left( {{t_2} + {t_3}} \right)} \right],\,\,\left[ {a{t_3}{t_1},\,a\left( {{t_3} + {t_1}} \right)} \right]$$. Find the orthocentre of the triangle.
$$\left[ {a{t_1}{t_2},\,\,a\left( {{t_1} + {t_2}} \right)} \right],\,\,\left[ {a{t_2}{t_3},a\left( {{t_2} + {t_3}} \right)} \right],\,\,\left[ {a{t_3}{t_1},\,a\left( {{t_3} + {t_1}} \right)} \right]$$. Find the orthocentre of the triangle.
28
Given positive integers $$r > 1,\,n > 2$$ and that the coefficient of $$\left( {3r} \right)$$th and $$\left( {r + 2} \right)$$th terms in the binomial expansion of $${\left( {1 + x} \right)^{2n}}$$ are equal. Then
29
The equation $$2{x^2} + 3x + 1 = 0$$ has an irrational root.
30
Find all real values of $$x$$ which satisfy $${x^2} - 3x + 2 > 0$$ and $${x^2} - 2x - 4 \le 0$$
31
If one root of the quadratic equation $$a{x^2} + bx + c = 0$$ is equal to the $$n$$-th power of the other, then show that
$$${\left( {a{c^n}} \right)^{{1 \over {n + 1}}}} + {\left( {{a^n}c} \right)^{{1 \over {n + 1}}}} + b = 0$$$
32
Prove that the complex numbers $${{z_1}}$$, $${{z_2}}$$ and the origin form an equilateral triangle only if $$z_1^2 + z_2^2 - {z_1}\,{z_2} = 0$$.
33
If $$z = x + iy$$ and $$\omega = \left( {1 - iz} \right)/\left( {z - i} \right),$$ then $$\,\left| \omega \right| = 1$$ implies that, in the complex plane,
34
Show that $$$16\cos \left( {{{2\pi } \over {15}}} \right)\cos \left( {{{4\pi } \over {15}}} \right)\cos \left( {{{8\pi } \over {15}}} \right)\cos \left( {{{16\pi } \over {15}}} \right) = 1$$$
35
If $$\tan \,A = \left( {1 - \cos B} \right)/\sin B,$$ then $$tan2A = tan\,B$$.
36
Find all solutions of $$4{\cos ^2}\,x\sin x - 2{\sin ^2}x = 3\sin x$$
37
Find the coordinates of the point on the curve $$y = {x \over {1 + {x^2}}}$$
where the tangent to the curve has the greatest slope.
where the tangent to the curve has the greatest slope.
38
Show that $$1+x$$ $$In\left( {x + \sqrt {{x^2} + 1} } \right) \ge \sqrt {1 + {x^2}} $$ for all $$x \ge 0$$
39
The function $$y = 2{x^2} - In\,\left| x \right|$$ is monotonically increasing for values of $$x\left( {x \ne 0} \right)$$ satisfying the inequalities ......... and monotonically decreasing for values of $$x$$ satisfying the inequalities ............
40
If $$y = a\,\,In\,x + b{x^2} + x$$ has its extreamum values at $$x=-1$$ and $$x=2$$, then
41
$$AB$$ is a diameter of a circle and $$C$$ is any point on the circumference of the circle. Then
42
The larger of $$\cos \left( {In\,\,\theta } \right)$$ and $$In $$ $$\left( {\cos \,\,\theta } \right)$$ If $${e^{ - \pi /2}} < \theta < {\pi \over 2}$$ is ..................
43
If $$x-r$$ is a factor of the polynomial $$f\left( x \right) = {a_n}{x^4} + ..... + {a_0},$$ repeated $$m$$ times $$\left( {1 < m \le n} \right)$$, then $$r$$ is a root of $$\left( x \right) = 0$$ repeated $$m$$ times.
44
Find all the solution of $$4$$ $${\cos ^2}x\sin x - 2{\sin ^2}x = 3\sin x$$
45
If $$a+b+c=0$$, then the quadratic equation $$3a{x^2} + 2bx + c = 0$$ has
46
The value of $$\tan \left[ {{{\cos }^{ - 1}}\left( {{4 \over 5}} \right) + {{\tan }^{ - 1}}\left( {{2 \over 3}} \right)} \right]$$ is
47
The points z1, z2, z3, z4 in the complex plane are the vertices of a parallelogram taken in order if and only if
48
The ex-radii $${r_1},{r_2},{r_3}$$ of $$\Delta $$$$ABC$$ are H.P. Show that its sides $$a, b, c$$ are in A.P.
49
The derivative of an even function is always an odd function.
50
From the top of a light-house 60 metres high with its base at the sea-level, the angle of depression of a boat is $${15^ \circ }$$. The distance of the boat from the foot of the light house is
51
The point of intersection of the line 4x - 3y - 10 = 0 and the circle $${x^2} + {y^2} - 2x + 4y - 20 = 0$$ are ........................and ...................
52
Through a fixed point (h, k) secants are drawn to the circle $$\,{x^2}\, + \,{y^2} = \,{r^2}$$. Show that the locus of the mid-points of the secants intercepted by the circle is $$\,{x^2}\, + \,{y^2} $$ = $$hx + ky$$.
53
The equation of the circle passing through (1, 1) and the points of intersection of $${x^2} + {y^2} + 13x - 3y = 0$$ and $$2{x^2} + 2{y^2} + 4x - 7y - 25 = 0$$ is
54
The centre of the circle passing through the point (0, 1) and touching the curve $$\,y = {x^2}$$ at (2, 4) is
55
Given the points $$A\left( {0,4} \right)$$ and $$B\left( {0, - 4} \right)$$, the equation of the locus of the point $$P\left( {x,y} \right)$$ such that $$\left| {AP - BP} \right| = 6$$ is .............
56
The coordinates of $$A, B, C$$ are $$(6, 3), (-3, 5), (4, -2)$$ respectively, and $$P$$ is any point $$(x, y)$$. Show that the ratio of the area of the triangles $$\Delta $$ $$PBC$$ and $$\Delta $$$$ABC$$ is $$\left| {{{x + y - 2} \over 7}} \right|$$
Physics
1
A river is flowing from west to east at a speed of 5 meters per minute. A man on the south bank of the river, capable of swimming at 10 meters per minute in still water, wants to swim across the river in the shortest time. He should swim in a direction
2
Two balls of different masses are thrown vertically upwards with the same speed. They pass through the point of projection in their downward motion with the same speed. (Neglect air resistance)
3
A particle moves in a circle of radius R. In half the period of revolution its displacement is ________ and distance covered is _________.
4
Match the physical quantities given in column I with dimension expressed in terms of mass (M), length (L), time (T), and charge (Q) given in column II and write the correct answer against the matched quantity in a tabular form in your answer book.
| Column I | Column II |
|---|---|
| Angular Momentum | ML2T-2 |
| Latent heat | ML2Q-2 |
| Torque | ML2T-1 |
| Capacitance | ML3T-1Q-2 |
| Inductance | M-1L-2T2Q2 |
| Resistivity | L2T-2 |