Which of the following relationships is valid only for reversible process undergone by a closed system of simple compressible substance (neglect changes in kinetic and potential energy?

For an ideal gas the expression $$\left[ {T{{\left( {{{\delta s} \over {\delta T}}} \right)}_p} - T{{\left( {{{\delta s} \over {\delta T}}} \right)}_v}} \right]$$ is always equal to :

A system undergoes a state change from $$1$$ to $$2.$$ According to the second law of thermodynamics, for the process to be feasible, the entropy changes, $${S_2} - {S_1}$$ of the system

A $$1500$$ $$W$$ electrical heater is used to heat $$20$$ $$kg$$ of water $$\left( {{C_p} = 4186\,\,J/kg\,\,K} \right)$$ in an insulated bucket, from a temperature of $${30^{^0}}C$$ to $${80^{^0}}C$$. If the heater temperature is only infinitesimally larger than the water temperature during the process, the change in entropy for the heater is ________$$J/K$$ and for water _______$$J/K.$$