For the reduction of silver ions with copper metal, the standard cell potential was found to be + 0.46 V at 25^oC. The value of standard Gibb's energy, $$\Delta $$G^o will be
(F = 96500 C mol^$$-$$1)

Al₂O₃ is reduced by electrolysis at low potentials and high currents. If 4.0 $$ \times $$ 10⁴ amperes of current is passed through molten Al₂O₃ for 6 hours, what mass of aluminium is product? (Assume 100% current efficiency, at mass of Al = 27 g mol^$$-$$1).

Given :
(i)   Cu²⁺ + 2e^$$-$$ $$ \to $$ Cu,  E^o = 0.337 V
(ii)  Cu²⁺ + e^$$-$$ $$ \to $$ Cu⁺,  E^o = 0.153 V
Electrode potential, E^o for the reaction,
Cu⁺ + e^$$-$$ $$ \to $$ Cu,  will be

The equivalent conductance of M/32 solution of a weak monobasic acid is 8.0 mho cm² and at infinite dilution is 400 mho cm². The dissociation constant of this acid is