Al₂O₃ is reduced by electrolysis at low potentials and high currents. If 4.0 $$ \times $$ 10⁴ amperes of current is passed through molten Al₂O₃ for 6 hours, what mass of aluminium is product? (Assume 100% current efficiency, at mass of Al = 27 g mol^$$-$$1).

Given :
(i)   Cu²⁺ + 2e^$$-$$ $$ \to $$ Cu,  E^o = 0.337 V
(ii)  Cu²⁺ + e^$$-$$ $$ \to $$ Cu⁺,  E^o = 0.153 V
Electrode potential, E^o for the reaction,
Cu⁺ + e^$$-$$ $$ \to $$ Cu,  will be

The equivalent conductance of M/32 solution of a weak monobasic acid is 8.0 mho cm² and at infinite dilution is 400 mho cm². The dissociation constant of this acid is

On the basis of the following E^o values, the strongest oxidizing agent is
[Fe(CN)₆]^4$$-$$ $$ \to $$ [Fe(CN)₆]^3$$-$$ + e^$$-$$;  E^o = $$-$$0.35 V

Fe²⁺ $$ \to $$ Fe³⁺ + e^$$-$$;  E^o = $$-$$0.77 V