Structure of Atom · Chemistry · NEET

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MCQ (Single Correct Answer)

1

The quantum numbers of four electrons are given below :

I. $$n=4 ; I=2 ; m_1=-2 ; s=-\frac{1}{2}$$

II. $$n=3 ; I=2 ; m_1=1 ; s=+\frac{1}{2}$$

III. $$n=4 ; I=1 ; m_1=0 ; s=+\frac{1}{2}$$

IV. $$n=3 ; I=1 ; m_1=-1 ; s=+\frac{1}{2}$$

The correct decreasing order of energy of these electrons is

NEET 2024 (Re-Examination)
2

Given below are two statements:

Statement I: The Balmer spectral line for H atom with lowest energy is located at $$\frac{5}{36} R_H \mathrm{~cm}^{-1}$$.

($$\mathrm{R}_{\mathrm{H}}=$$ Rydberg constant)

Statement II: When the temperature of blackbody increases, the maxima of the curve (intensity and wavelength) shifts to shorter wavelength.

In the light of the above statements, choose the correct answer from the options given below:

NEET 2024 (Re-Examination)
3

The energy of an electron in the ground state $$\mathrm{(n=1)}$$ for $$\mathrm{He}^{+}$$ ion is $$\mathrm{-x} \mathrm{~J}$$, then that for an electron in $$\mathrm{(n=2)}$$ state for $$\mathrm{Be}^{3+}$$ ion in $$\mathrm{J}$$ is

NEET 2024
4

Match List I with List II.

List I
(Quantum Number)
List II
(Information provided)
A. $$\mathrm{m_l}$$ I. Shape of orbital
B. $$\mathrm{m_s}$$ II. Size of orbital
C. I III. Orientation of orbital
D. n IV. Orientation of spin of electron

Choose the correct answer from the options given below :

NEET 2024
5

Incorrect set of quantum numbers from the following is :

NEET 2023 Manipur
6

Given below are two statements:

Statement I : The value of wave function, $$\psi $$ depends upon the coordinates of the electron in the atom.

Statement II : The probability of finding an electron at a point within an atom is proportional to the orbital wave function.

In the light of the above statements, choose the correct answer from the options given below:

NEET 2023 Manipur
7

Select the correct Statements from the following :

A. Atoms of all elements are composed of two fundamental particles.

B. The mass of the electron is $$9.10939 \times 10^{-31} \mathrm{~kg}$$.

C. All the isotopes of a given elements show same chemical properties.

D. Protons and electrons are collectively known as nucleons.

E. Dalton's atomic theory, regarded the atom as an ultimate particle of matter.

Choose the correct answer from the options given below.

NEET 2023
8

The relation between $$\mathrm{n}_{\mathrm{m}},\left(\mathrm{n}_{\mathrm{m}}=\right.$$ the number of permissible values of magnetic quantum number $$(\mathrm{m})$$) for a given value of azimuthal quantum number $$(l)$$, is

NEET 2023
9

Match List-I with List-II :

List-I
(quantum number)
List-II
(orbital)
(a) n = 2, l = 1 (i) 2s
(b) n = 3, l = 2 (ii) 3s
(c) n = 3, l = 0 (iii) 2p
(d) n = 2, l = 0 (iv) 3d

Choose the correct answer from the options given below :

NEET 2022 Phase 2
10

When electromagnetic radiation of wavelength 300 nm falls on the surface of a metal, electrons are emitted with the kinetic energy of 1.68 $$\times$$ 105 J mol$$-$$1. What is the minimum energy needed to remove an electron from the metal?

(h = 6.626 $$\times$$ 10$$-$$34 Js, c = 3 $$\times$$ 108 ms$$-$$1, NA = 6.022 $$\times$$ 1023 mol$$-$$1)

NEET 2022 Phase 2
11

Identify the incorrect statement from the following.

NEET 2022 Phase 1
12

If radius of second Bohr orbit of the He+ ion is 105.8 pm, what is the radius of third Bohr orbit of Li2+ ion?

NEET 2022 Phase 1
13
A particular station of All India Radio, New Delhi broadcasts on a frequency of 1,368 kHz (kilohertz). The wavelength of the electromagnetic radiation emitted by the transmitter is : [speed of light c = 3.0 $$\times$$ 108 ms$$-$$1]
NEET 2021
14
From the following pairs of ions which one is not an iso-electronic pair?
NEET 2021
15
4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is :
NEET 2019
16
Which of the following series of transitions in the spectrum of hydrogen atom falls in visible region?
NEET 2019
17
Which one is a wrong statement?
NEET 2018
18
Which one is the wrong statement ?
NEET 2017
19
How many electrons can fit in the orbital for which n = 3 and $$l$$ = 1?
NEET 2016 Phase 2
20
Which of the following pairs of d-orbitals will have electron density along the axes ?
NEET 2016 Phase 2
21
Two electrons occupying the same orbital are distinguished by
NEET 2016 Phase 1
22
Which is the correct order of increasing energy of the listed orbitals in the atom of titanium ? (At. no. Z = 22)
AIPMT 2015
23
The number of d-electrons in Fe2+ (Z = 26) is not equal to the number of electrons in which one of the following ?
AIPMT 2015 Cancelled Paper
24
The angular momentum of electron in 'd' orbital is equal to
AIPMT 2015 Cancelled Paper
25
Calculate the energy in joule corresponding to light of wavelength 45 nm. (Planck,s constant, h = 6.63 $$ \times $$ 10$$-$$34 J s, speed of light, c = 3 $$ \times $$ 108 m s$$-$$1)
AIPMT 2014
26
Be2+ is isoelectronic with which of the following ions ?
AIPMT 2014
27
What is the maximum number of orbitals that can be identified with the following quantum numbers ?
n = 3, l = 1, m1 = 0
AIPMT 2014
28
According to law of photochemical equivalence the energy absorbed (in ergs/mole) is given as (h = 6.62 $$ \times $$ 10$$-$$27 ergs, c = 3 $$ \times $$ 1010 cm s$$-$$1, NA = 6.02 $$ \times $$ 10$$-$$23 mol$$-$$1)
NEET 2013 (Karnataka)
29
The outer electronic configuration of Gd (At. No. 64) is
NEET 2013 (Karnataka)
30
The value of Planck's constant is 6.63 $$ \times $$ 10$$-$$34 J s. The speed of light is 3 $$ \times $$ 1017 mm s$$-$$1. Which value is closest to the wavelength in nanometer of a quantum of light with frequency of 6 $$ \times $$ 1015 s$$-$$1 ?
NEET 2013
31
What is the maximum numbers of electrons that can be associated with the following set of quantum numbers ?
n = 3, $$l$$ = 1 and m = $$-$$ 1
NEET 2013
32
Based on equation E = $$-$$ 2.178 $$ \times $$ 10$$-$$18 J $$\left( {{{{Z^2}} \over {{n^2}}}} \right)$$, certain conclusions are written. Which of them is not correct ?
NEET 2013
33
The orbital angular momentum of a p-electron is given as
AIPMT 2012 Mains
34
Maximum number of electrons in a subshell with $$l$$ = 3 and n = 4 is
AIPMT 2012 Prelims
35
The correct set of four quantum numbers for the valence electron of rubidium atom (Z = 37) is
AIPMT 2012 Prelims
36
According to the Bohr theory, which of the following transitions in the hydrogen atom will give rise to the least energetic photon ?
AIPMT 2011 Mains
37
The total number of atomic orbitals in fourth energy level of an atom is
AIPMT 2011 Prelims
38
The energies E1 and E2 of two radiations are 25 eV and 50 eV respectively. The relation between their wavelengths i.e., $$\lambda $$1 and $$\lambda $$2 will be
AIPMT 2011 Prelims
39
If n = 6, the correct sequence for filling of electrons will be
AIPMT 2011 Prelims
40
A 0.66 kg ball is moving with a speed of 100 m/s. The associated wavelength will be

(h = 6.6 $$ \times $$ 10$$-$$34 J s)
AIPMT 2010 Mains
41
Maximum number of electrons in a subshell of an atom is determined by the following
AIPMT 2009
42
Which of the following is not permissible arrangement of electrons in an atom ?
AIPMT 2009
43
If uncertainty in position and momentum are equal, then uncertainty in velocity is
AIPMT 2008
44
The measurement of the electron position is associated with an uncertainty in momentum, which is equal to 1 $$ \times $$ 10$$-$$18 g cm s$$-$$1. The uncertainty in electron velocity is (mass of an electron is 9 $$ \times $$ 10$$-$$28 g)
AIPMT 2008
45
Consider the following sets of quantum numbers :

n l m s
(i) 3 0 0 +1/2
(ii) 2 2 1 +1/2
(iii) 4 3 -2 -1/2
(iv) 1 0 -1 -1/2
(v) 3 2 3 +1/2


Which of the following sets of quantum number is not possible ?
AIPMT 2007
46
Given : The mass of electron is 9.11 $$ \times $$ 10$$-$$31 kg, Planck constant is 6.626 $$ \times $$ 10$$-$$34 J s, the uncertainty involved in the measurement of velocity within a distance of 0.1 $$\mathop A\limits^ \circ $$ is
AIPMT 2006
47
The orientation of an atomic orbital is governed by
AIPMT 2006
48
The energy of second Bohr orbit of the hydrogen atom is $$-$$328 kJ mol$$-$$1; hence the energy of fourth Bohr orbit would be
AIPMT 2005
49
The frequency of radiation emitted when the electron falls from n = 4 to n = 1 in hydrogen atom will be (Given ionization energy of H = 2.18 $$ \times $$ 10$$-$$18 J atom$$-$$1 and h = 6.625 $$ \times $$ 10$$-$$34 J s)
AIPMT 2004
50
The velocity of Planck's constant is 6.63 $$ \times $$ 10$$-$$34 J s.

The velocity of light is 3.0 $$ \times $$ 108 m s$$-$$1. Which value is closest to the wavelength in nanometers of a quantum of light with frequency of 8 $$ \times $$ 1015 s$$-$$1 ?
AIPMT 2003
51
In hydrogen atom, energy of first excited state is $$-$$ 3.4 eV. Then find out K.E. of same orbit of hydrogen atom
AIPMT 2002
52
Main axis of a diatomic molecule is z, molecular orbital px and py overlap to from which of the following orbitals.
AIPMT 2001
53
The following quantum numbers are possible for how many orbitals :

n = 3, $$l$$ = 2, m = +2 ?
AIPMT 2001
54
Isoelectronic species are
AIPMT 2000
55
For given energy, E = 3.03 $$ \times $$ 10$$-$$19 Joules corresponding wavelength is (h = 6.626 $$ \times $$ 10$$-$$34 J sec, c = 3 $$ \times $$ 108 m/sec)
AIPMT 2000
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