Chemical Bonding and Molecular Structure · Chemistry · NEET

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MCQ (Single Correct Answer)

1

Which of the following molecules has "NON ZERO" dipole moment value?

NEET 2024 (Re-Examination)
2

Arrange the following compounds in increasing order of their solubilities in chloroform: $$\mathrm{NaCl}, \mathrm{CH}_3 \mathrm{OH}$$, cyclohexane, $$\mathrm{CH}_3 \mathrm{CN}$$

NEET 2024 (Re-Examination)
3

Identify the incorrect statement about $$\mathrm{PCl}_5$$.

NEET 2024 (Re-Examination)
4

Match List-I with List-II:

List - I
Molecule
List - II
Bond enthalpy (kJ mol$$^{-1}$$)
(A) HCl (I) 435.8
(B) N$$_2$$ (II) 498
(C) H$$_2$$ (III) 946.0
(D) O$$_2$$ (IV) 431.0

Choose the correct answer from the options given below:

NEET 2024 (Re-Examination)
5

Match List I with List II.

List I
(Molecule)
List II
(Number and types of bond/s between two carbon atoms)
A. ethane I. one $$\sigma$$-bond and two $$\pi$$-bonds
B. ethene II. two $$\pi$$-bonds
C. carbon molecule, C$$_2$$ III. one $$\sigma$$-bond
D. ethyne IV. one $$\sigma$$-bond and one $$\pi$$-bond

Choose the correct answer from the options given below :

NEET 2024
6

Given below are two statements:

Statement I: The boiling point of hydrides of Group 16 elements follow the order $$\mathrm{H}_2 \mathrm{O}>\mathrm{H}_2 \mathrm{Te}>\mathrm{H}_2 \mathrm{Se}>\mathrm{H}_2 \mathrm{S} \text {. }$$

Statement II: On the basis of molecular mass, $$\mathrm{H}_2 \mathrm{O}$$ is expected to have lower boiling point than the other members of the group but due to the presence of extensive $$\mathrm{H}$$-bonding in $$\mathrm{H}_2 \mathrm{O}$$, it has higher boiling point.

In the light of the above statements, choose the correct answer from the options given below:

NEET 2024
7

Intramolecular hydrogen bonding is present in

NEET 2024
8

Match List I with List II.

List I
(Compound)
List II
(Shape/geometry)
A. NH$$_3$$ I. Trigonal Pyramidal
B. BrF$$_5$$ II. Square Planar
C. XeF$$_4$$ III. Octahedral
D. SF$$_6$$ IV. Square Pyramidal

Choose the correct answer from the options given below:

NEET 2024
9

Identify the correct answer.

NEET 2024
10

The correct order of dipole moments for molecules $$\mathrm{NH}_3, \mathrm{H}_2 \mathrm{~S}, \mathrm{CH}_4$$ and $$\mathrm{HF}$$, is:

NEET 2023 Manipur
11

Which one of the following represents all isoelectronic species ?

NEET 2023 Manipur
12

Which one of the following statements is incorrect related to Molecular Orbital Theory?

NEET 2023 Manipur
13

Given below are two statements:

Statement I : Hydrated chlorides and bromides of $$\mathrm{Ca}, \mathrm{Sr}$$ and $$\mathrm{Ba}$$ on heating undergo hydrolysis.

Statement II : Hydrated chlorides and bromides of $$\mathrm{Be}$$ and $$\mathrm{Mg}$$ on heating undergo dehydration.

In the light of the above statements, choose the correct answer from the options given below :

NEET 2023 Manipur
14

Amongst the following, the total number of species NOT having eight electrons around central atom in its outer most shell, is

$$\mathrm{NH}_{3}, \mathrm{AlCl}_{3}, \mathrm{BeCl}_{2}, \mathrm{CCl}_{4}, \mathrm{PCl}_{5}$$ :

NEET 2023
15

The correct order of energies of molecular orbitals of $$\mathrm{N}_{2}$$ molecule, is

NEET 2023
16

Taking stability as the factor, which one of the following represents correct relationship?

NEET 2023
17

Intermolecular forces are forces of attraction and repulsion between interacting particles that will include:

A. dipole - dipole forces.

B. dipole - induced dipole forces

C. hydrogen bonding

D. covalent bonding

E. dispersion forces

Choose the most appropriate answer from the options given below :

NEET 2023
18

Match List-I with List-II :

List-I
(Molecules)
List-II
(Shape)
(a) NH$$_3$$ (i) Square pyramidal
(b) ClF$$_3$$ (ii) Trigonal bipyramidal
(c) PCl$$_5$$ (iii) Trigonal pyramidal
(d) BrF$$_5$$ (iv) T-shape

Choose the correct answer from the options given below :

NEET 2022 Phase 2
19

The correct order of bond angles in the following compounds/species is :

NEET 2022 Phase 2
20

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R)

Assertion (A) : ICI is more reactive than I2

Reason (R) : I-CI bond is weaker than I-I bond.

In the light of the above statements, choose the most appropriate answer from the options given below:

NEET 2022 Phase 1
21

Amongst the following which one will have maximum 'lone pair - lone pair' electron repulsions?

NEET 2022 Phase 1
22

Which amongst the following is incorrect statement?

NEET 2022 Phase 1
23
BF3 is planar and electron deficient compound. Hybridization and number of electrons around the central atom, respectively are :
NEET 2021
24
Match List - I with List - II :

List - I List - II
(a) $$PC{l_5}$$ (i) Square pyramidal
(b) $$S{F_6}$$ (ii) Trigonal planar
(c) $$Br{F_5}$$ (iii) Octahedral
(d) $$B{F_3}$$ (iv) Trigonal bipyramidal


Choose the correct answer from the options given below.
NEET 2021
25
The correct sequence of bond enthalpy of 'C-X' bond is :
NEET 2021
26
Which of the following molecules is non-polar in nature?
NEET 2021
27
Which of the following set of molecules will have zero dipole moment?
NEET 2020 Phase 1
28
Identify a molecule which does not exist.
NEET 2020 Phase 1
29
Which of the following diatomic molecular species has only $$\pi $$ bonds according to Molecular Orbital Theory?
NEET 2019
30
The correct structure of tribromooctaoxide is :
NEET 2019
31
The manganate and permanganate ions are tetrahedral due to :
NEET 2019
32
The number of sigma ($$\sigma $$) and pi ($$\pi $$) bonds in pent-2-en-4-yne is -
NEET 2019
33
In the structure of ClF3 , the number of lone pairs of electrons on central atom ‘Cl’ is
NEET 2018
34
Consider the following species : CN+ , CN , NO and CN. Which one of these will have the highest bond order?
NEET 2018
35
Which one of the following pairs of species have the same bond order ?
NEET 2017
36
The species, having bond angles of 120o is
NEET 2017
37
Which one of the following compounds shows the presence of intramolecular hydrogen bond?
NEET 2016 Phase 2
38
The hybridizations of atomic orbitals of nitrogen in NO$$_2^ + $$, NO$$_3^ - $$  and  NH$$_4^ + $$  respectively are
NEET 2016 Phase 2
39
Among the following, which one is a wrong statement ?
NEET 2016 Phase 2
40
The correct geometry and hybridization for XeF4 are
NEET 2016 Phase 2
41
Predict the correct order among the following :
NEET 2016 Phase 1
42
Consider the molecules CH4, NH3 and H2O.

Which of the given statements is false?
NEET 2016 Phase 1
43
In which of the following pairs, both the species are not isostructural ?
AIPMT 2015
44
Decreasing order of stability of O2, O2$$-$$, O2+ and O22$$-$$ is
AIPMT 2015
45
Which of the following pairs of ions are isoelectronic and isostructural ?
AIPMT 2015 Cancelled Paper
46
Which of the following species contains equal number of $$\sigma $$- and $$\pi $$-bonds ?
AIPMT 2015 Cancelled Paper
47
Which of the following options represents the correct bond order ?
AIPMT 2015 Cancelled Paper
48
Maximum bond angle at nitrogen is present in which of the following ?
AIPMT 2015 Cancelled Paper
49
The correct bond order in the following species is
AIPMT 2015 Cancelled Paper
50
Which one of the following species has plane triangular shape ?
AIPMT 2014
51
Which of the following molecules has the maximum dipole moment ?
AIPMT 2014
52
In which of the following pair both the species have sp3 hybridization ?
NEET 2013 (Karnataka)
53
The pair of species that has the same bond order in the following is
NEET 2013 (Karnataka)
54
The outer orbitals of C in ethane molecule can be considered to be hybridized to give three equivalent sp2 orbitals. The total number of sigma $$\left( \sigma \right)$$ and pi $$\left( \pi \right)$$ bonds in ethane molecule is
NEET 2013 (Karnataka)
55
In which of the following ionization processes the bond energy increases and the magnetic behaviour changes from paramagnetic to diamagnetic.
NEET 2013 (Karnataka)
56
Which of the following is paramagnetic?
NEET 2013
57
Which of the following is a polar molecule?
NEET 2013
58
Dipole-induced dipole interactions are present in which of the following pairs
NEET 2013
59
XeF2 is isostructural with
NEET 2013
60
Which of the following is electron-deficient ?
NEET 2013
61
Identify the correct order of solubility in aqueous medium.
NEET 2013
62
During change of O2 to O$$_2^{ - }$$ ion, the electron adds on which one of the following orbitals ?
AIPMT 2012 Mains
63
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
AIPMT 2012 Mains
64
Bond order of 1.5 is shown by
AIPMT 2012 Prelims
65
Which one of the following pairs is isostructural (i.e., having the same shape and hybridization) ?
AIPMT 2012 Prelims
66
The pair of species with the same bond order is
AIPMT 2012 Prelims
67
Which of the following species contains three bond pairs and one lone pair arround the central atom ?
AIPMT 2012 Prelims
68
Which of the following structures is the most preferred and hence of lowest energy for SO3?
AIPMT 2011 Mains
69
The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the following presents the correct description?
AIPMT 2011 Mains
70
The pairs of species of oxygen and their magnetic behavior are noted below. Which of the following presents the correct description?
AIPMT 2011 Prelims
71
Which of the two ions from the list given below that have the geometry that is explained by the same hybridization of orbitals, NO$$_2^ - $$. NO$$_3^ - $$, NH$$_2^ - $$, NH$$_4^ + $$, SCN$$-$$?
AIPMT 2011 Prelims
72
The correct order of increasing bond length of C $$-$$ H, C $$-$$ O, C $$-$$ C and C$$=$$C is
AIPMT 2011 Prelims
73
Which of the following has the minimum bond length ?
AIPMT 2011 Prelims
74
In which of the following molecules the central atom does not have sp3 hybridization?
AIPMT 2010 Mains
75
Some of the properties of the two species, $$NO_3^ - $$ and $${H_3}{O^ + }$$ are described below. Which one of them is current?
AIPMT 2010 Mains
76
In which one of the following species the central atom has the type of hybridization which is not the same as that present in the other three ?
AIPMT 2010 Prelims
77
Which one of the following species does not exist under normal conditions?
AIPMT 2010 Prelims
78
In which of the following pairs of molecules/ ions, the central atoms have sp2 hybridisation ?
AIPMT 2010 Prelims
79
According to MO theory which of the lists ranks the nitrogen species in terms of increasing bond order ?
AIPMT 2009
80
In which of the following molecules/ions BF3, NO$$_2^ - $$, NH$$_2^ - $$ and H2O, the central atom is sp2 hybridised?
AIPMT 2009
81
What is the dominant intermolecular force or bond that must be overcome in converting liquid CH3OH to a gas?
AIPMT 2009
82
Four diatomic species are listed below. Identify the correct order in which the bond order is increasing in them
AIPMT 2008
83
The correct order of increasing bond angles in the following triatomic species is
AIPMT 2008
84
The correct order of C $$-$$ O bond length among CO, CO$${_3^{2 - }}$$, CO2 is
AIPMT 2007
85
In which of the following pairs, the two species are isostructural?
AIPMT 2007
86
The electronegativity difference berween N and F is greater than that between N and H yet the dipole moment of NH3 (1.5D) is larger than that of NF3 (0.2 D). This is because
AIPMT 2006
87
Which of the following is not a correct statement?
AIPMT 2006
88
Which of the following is not isostructural with SiCl4 ?
AIPMT 2006
89
Which of the following species has a linear shape?
AIPMT 2006
90
The correct sequence of increasing covalent character is represented by
AIPMT 2005
91
Which of the following would have a permanent dipole moment?
AIPMT 2005
92
The surface tension of which of the following liquid is maximum ?
AIPMT 2005
93
Which of the following molecules has trigonal planar geometry?
AIPMT 2005
94
The correct order in which the O $$-$$ O bond length increases in the following is
AIPMT 2005
95
In BrF3 molecule, the lone pairs occupy equatorial positions to minimize
AIPMT 2004
96
Among the following, the pair in which the two species are not isostructural is
AIPMT 2004
97
H2O is dipolar, whereas BeF2 is not. It is because
AIPMT 2004
98
In a regular octahedral molecule, MX6 the number of X $$-$$ M $$-$$ X bonds at 180o is
AIPMT 2004
99
Which one of the following statements is not correct for sigma- and pi- bonds formed between two carbon atoms?
AIPMT 2003
100
Which of the following has p$$\pi $$ $$-$$ d$$\pi $$ bonding?
AIPMT 2002
101
In NO3$$-$$ ion number of bond pair and lone pair of electrons on nitrogen atom are
AIPMT 2002
102
Which of the following is isoelectronic?
AIPMT 2002
103
In X - H --- Y, X and Y both are electronegative elements. Then
AIPMT 2001
104
In which of the following bond angle is maximum ?
AIPMT 2001
105
Nitrogen forms N2, but phosphorus does not form P2, however, it converts P4, reason is
AIPMT 2001
106
Which of the following two are isostructural?
AIPMT 2001
107
Which species does not exhibit paramagnetism?
AIPMT 2000
108
Which compound has planar structure?
AIPMT 2000
109
Right order of dissociation energy N2 and N2+ is
AIPMT 2000
110
d$$\pi $$ $$-$$ p$$\pi $$ bond present in
AIPMT 2000

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