1
MCQ (Single Correct Answer)

NEET 2013 (Karnataka)

Consider the half-cell reduction reaction
Mn2+ + 2e$$-$$ $$ \to $$ Mn, Eo = $$-$$1.18 V
Mn2+ $$ \to $$ Mn3+ + e$$-$$, Eo = $$-$$ 1.51 V
The $$E$$o for the reaction 3 Mn2+ $$ \to $$ Mno + 2Mn3+, and possibility of the forward reaction are respectively
A
$$-$$ 4.18 V and yes
B
+ 0.33 V and yes
C
+ 2.69 V and no
D
$$-$$ 2.69 V and no

Explanation

Mn2+ + 2e$$-$$ $$ \to $$ Mn, Eo = $$-$$1.18 V

Mn2+ $$ \to $$ Mn3+ + e$$-$$, Eo = $$-$$ 1.51 V

3Mn2+ $$ \to $$ Mno + 2Mn3+, $$\Delta $$Eo = - 1.81 - 1.51 = $$-$$ 2.69 V

Since $$\Delta $$E° is negative,

$$ \therefore $$ $$\Delta $$G = –nFE°, $$\Delta $$G will have positive value so, forward reaction is not possible.
2
MCQ (Single Correct Answer)

NEET 2013

At 25oC molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm$$-$$1 cm2 mol$$-$$1 and at infinite dilution its molar conductance is 238 ohm$$-$$1 cm2 mol$$-$$1. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is
A
4.008%
B
40.800%
C
2.080%
D
20.800%

Explanation

Degree of dissociation($$\alpha $$) = $${{9.54} \over {238}}$$ = 0.04008 = 4.008%
3
MCQ (Single Correct Answer)

NEET 2013

A button cell used in watches function as following.
Zn(s) + Ag2O(s) + H2O(l) $$\rightleftharpoons$$ 2Ag(s) + Zn2+(aq) + 2OH$$-$$(aq)

If half cell potentials are
Zn2+(aq) + 2e$$-$$ $$ \to $$ Zn(s);  Eo = $$-$$0.76 V
Ag2O(s) + H2O(l) + 2e$$-$$ $$ \to $$ 2Ag(s) + 2OH$$-$$(aq), Eo = 0.34 V

The cell potential will be
A
0.84 V
B
1.34 V
C
1.10 V
D
0.42 V

Explanation

At anode :Zn2+(aq) + 2e$$-$$ $$ \to $$ Zn(s);  Eo = $$-$$0.76 V

At cathode : Ag2O(s) + H2O(l) + 2e$$-$$ $$ \to $$ 2Ag(s) + 2OH$$-$$(aq), Eo = 0.34 V

cell = E°cathode – E°anode

= 0.34 – (–0.76) = 1.10 V
4
MCQ (Single Correct Answer)

AIPMT 2012 Mains

Molar conductivities $$\left( {\Lambda _m^o} \right)$$ at infinite dilution of NaCl, Hcl and CH3COONa are 126.4, 425.9 and 91.0 S cm2 mol$$-$$1 respectively. $$\left( {\Lambda _m^o} \right)$$ for CH3COOH will be
A
425.5 S cm2 mol$$-$$1
B
180.5 S cm2 mol$$-$$1
C
290.8 S cm2 mol$$-$$1
D
390.5 S cm2 mol$$-$$1

Explanation

$$\Lambda $$oCH3COOH = $$\Lambda $$oCH3COONa + $$\Lambda $$oHCl - $$\Lambda $$oNaCl

= = 91 + 425.9 – 126.4 = 390.5

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