7
The correct structure of 2, 6-dimethyl-dec-4-ene is
8
As alkene on ozonolysis gives methanal as one of the product, Its structure is :
9
Among the following, the reaction that proceeds through an electrophilic substitution, is :
11
An alkene “A” on reaction with O3 and Zn + H2O gives propanone and ethanal in equimolar ratio. Addition
of HCl to alkene “A” gives “B” as the major product. The structure of product “B” is :
12
Hydrocarbon (A) reacts with bromine by
substitution to form an alkyl bromide which by
Wurtz reaction is converted to gaseous
hydrocarbon containing less than four carbon
atoms. (A) is
13
Predict the correct intermediate and product in the following reaction :
$${H_3}C - C \equiv CH\mathrel{\mathop{\kern0pt\longrightarrow}
\limits_{HgS{O_4}}^{{H_2}O,{H_2}S{O_4}}} \mathop {Intermediate}\limits_{(A)} \to \mathop {\Pr oduct}\limits_{(B)} $$
14
Which one is the correct order of acidity?
15
With respect to the conformers of ethane, which of the following statements is true?
16
The compound that will react most readily with gaseous bromine has the formula
18
Which of the following compounds shall not produce propene by reaction with HBr followed by elimination or direct only elimination reaction ?
20
Which of the following can be used as the halide component for Friedel-Crafts reaction?
21
In which of the following molecules, all atoms are coplanar?
23
The pair of electrons in the given carbanion, CH3C $$ \equiv $$ C$$-$$, is present in which of the following orbitals?
24
Consider the nitration of benzene using mixed conc.H2SO4 and HNO3. If a large amount of KHSO4 is added to the mixture, the rate of nitration will be
27
In the reaction with HCl, an alkene reacts in accordance with the Markovnikov's rule to give a product 1-chloro-1 methylcyclohexane. The possible alkene is
28
2,3-Dimethyl-2-butene can be prepared by heating which of the following compounds with a strong acid?
33
Which of the following organic compounds has same hybridization as its combustion product (CO2)?
35
Which of the following compounds will not undergo Friedal-Craft's reaction easily?
36
Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?
38
Among the following compounds the one that is most reactive towards electrophilic nitration is
39
Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by
40
The reaction of toluene with Cl2 in presence of FeCl3 gives X and reaction in presence of light gives Y. Thus, X and Y are
42
Benzene reacts with CH3Cl in the presence of anhydrons AlCl3 to form
43
Which of the following compounds will exhibit cis-trans (geometrical) isomerism?
47
Which of the compound with molecular formula C5H10 yields acetone on ozonolysis?
49
Which one of the following alkenes will react faster with H2 under catalytic hydrogenation conditions ?
51
Reaction of HBr with propene in the presence of peroxide gives
52
Using anhydrous AlCl3 as catalyst, which one of the following reactions produces ethylbenzene (PhEt)?
53
The correct order of reactivity towards the electrophilic substitution of the compounds aniline (I), benzene (II) and nitrobenzene (III) is
54
Which one of the following is a free-radical substitution reaction ?
56
When CH3CH2CHCl2 is treated with NaNH2, the product formed is
57
In preparation of alkene from alcohol using Al2O3 which is the effective factor ?
58
2-Butene shows geometrical isomerism due to
59
Which reagent converts propene to 1-propanol ?
61
In Friedel-Crafts reaction , toluene can be prepared by
63
Dihedral angle in staggered form of ethane is