The conductivity of centimolar solution of $$\mathrm{KCl}$$ at $$25^{\circ} \mathrm{C}$$ is $$0.0210 ~\mathrm{ohm}^{-1} \mathrm{~cm}^{-1}$$ and the resistance of the cell containing the solution at $$25^{\circ} \mathrm{C}$$ is $$60 ~\mathrm{ohm}$$. The value of cell constant is -
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R:
Assertion A : In equation $$\mathrm{\Delta_rG=-nFE_{cell}}$$, value of $$\mathrm{\Delta_rG}$$ depends on n.
Reason R : $$\mathrm{E_{cell}}$$ is an intensive property and $$\mathrm{\Delta_rG}$$ is an extensive property.
In the light of the above statements, choose the correct answer from the options given below:
Two half cell reactions are given below.
$$C{o^{3 + }} + {e^ - } \to C{o^{2 + }},\,\,\,\,\,\,\,\,\,E_{C{o^{2 + }}/C{o^{3 + }}}^0 = - 1.81\,V$$
$$2A{l^{3 + }} + 6{e^ - } \to 2Al(s),\,\,\,E_{Al/A{l^{3 + }}}^0 = + 1.66\,V$$
The standard EMF of a cell with feasible redox reaction will be :
Standard electrode potential for the cell with cell reaction
Zn(s) + Cu2+(aq) $$\to$$ Zn2+(aq) + Cu(s)
is 1.1 V. Calculate the standard Gibbs energy change for the cell reaction. (Given F = 96487 C mol$$-$$1)