1
AIPMT 2010 Mains
MCQ (Single Correct Answer)
+4
-1
Consider the following relations for emf of an electrochemical cell
(i)   EMF of cell = (Oxidation potential of anode) $$-$$ (Reduction potential of cathode)
(ii)  EMF of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(iii) EMF of cell = (Reductional potential of anode) + (Reduction potential of cathode)
(iv) EMF of cell = (Oxidation potential of anode) $$-$$ (Oxidation potential of cathode)

Which of the above relations are correct?
A
(iii) and (i)
B
(i) and (ii)
C
(iii) and (iv)
D
(ii) and (iv)
2
AIPMT 2010 Prelims
MCQ (Single Correct Answer)
+4
-1
For the reduction of silver ions with copper metal, the standard cell potential was found to be + 0.46 V at 25oC. The value of standard Gibb's energy, $$\Delta $$Go will be
(F = 96500 C mol$$-$$1)
A
$$-$$ 89.0 kJ
B
$$-$$ 89.0 J
C
$$-$$ 44.5 kJ
D
$$-$$ 98.0 kJ
3
AIPMT 2010 Prelims
MCQ (Single Correct Answer)
+4
-1
An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to
A
increase in ionic mobility of ions
B
100% ionisation of electrolyte at normal dilution
C
increase in both i.e., number of ions and ionic mobility of ions
D
increase in number of ions.
4
AIPMT 2009
MCQ (Single Correct Answer)
+4
-1
Al2O3 is reduced by electrolysis at low potentials and high currents. If 4.0 $$ \times $$ 104 amperes of current is passed through molten Al2O3 for 6 hours, what mass of aluminium is product? (Assume 100% current efficiency, at mass of Al = 27 g mol$$-$$1).
A
8.1 $$ \times $$ 104 g
B
2.4 $$ \times $$ 105 g
C
1.3 $$ \times $$ 104 g
D
9.0 $$ \times $$ 103 g

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