7
Choose the correct option for graphical representation of Boyle's law, which shows a graph of pressure vs. volume of a gas at different temperatures :
8
Choose the correct option for the total pressure (in atm.) in a mixture of 4g O2 and 2g H2 confined in a total volume of one litre at 0$$^\circ$$C is :
[Given R = 0.082 L atm mol$$-$$1K$$-$$1, T = 273 K]
9
A mixture of N2 and Ar gases in a cylinder contains 7g of N2 and 8g of Ar. If the total pressure of the mixture of the gases in the cylinder is 27 bar, the partial pressure of N2 is :
[Use atomic masses (in g mol$$ - $$1) : N = 14, Ar = 40]
10
A gas at 350 K and 15 bar has molar volume 20 percent smaller than that for an ideal gas under the same
conditions. The correct option about the gas and its compressibility factor (Z) is -
11
The correction factor ‘a’ to the ideal gas
equation corresponds to
12
Given van der Waals’ constant for NH3
, H2,
O2
and CO2
are respectively 4.17, 0.244, 1.36
and 3.59, which one of the following gases is
most easily liquefied?
13
Equal moles of hydrogen and oxygen gases are placed in a container with a pin-hole through which both can escape. What fraction of the oxygen escapes in the time required for onehalf of the hydrogen to escape?
14
A gas such as carbon monoxide would be most likely to obey the ideal gas law at
15
What is the density of N2 gas 227oC and 5.00 atm. pressure? (R = 0.082 L atm K$$-$$1 mol$$-$$1)
16
Maximum deviation from ideal gas is expected from
17
Equal volumes of two monoatomic gases, A and B at same temperature and pressure are mixed. The ratio of specific heats (Cp/Cv) of the mixture will be
18
For real gases van der Waals equation is written as
$$\left( {p + {{a{n^2}} \over {{V^2}}}} \right)$$ (V $$-$$ nb) = n RT
where $$a$$ and $$b$$ are van der Waals constants. Two sets of gases are
(I) O2, CO2, H2 and He
(II) CH4. O2 and H2
The gases given in set-I in increasing order of b and gases given in set-II in decreasing order of $$a$$, are arranged below. Select the correct order from the following
19
A certain gas takes three times as long to effuse out as helium. Its molecular mass will be
20
50 mL of each gas A and of gas B takes 150 and 200 seconds respectively for effusing through a pin hole under the similar conditions. If molecular mass of gas B is 36, the molecular mass of gass A will be
21
A bubble of air is underwater at temperature 15oC and the pressure 1.5 bar. If the bubble rises to the surface where the temperature is 25oC and the pressure is 1.0 bar, what will happen to the volume of the bubble?
22
In Duma's method of estimation of nitrogen 0.35 g of an organic compound gave 55 mLof nitrogen collected at 300 K temperature and 715 mm pressure. The percentage composition of nitrogen in the compound would be (aqueous tension at 300 K = 15 mm).
23
Two gases A and B having the same volume diffuse through a porous partition in 20 and 10 seconds respectively. The molecular mass of A is 49 u. Molecular mass of B will be
24
A gaseous mixture was prepared by taking equal mole of CO and N2. If the total pressure of the mixture was found 1 atmosphere, the partial pressure of the nitrogen (N2) in the mixture is
25
By what factor does the average velocity of a gaseous molecule increase when the temperature (in Kelvin) is doubled ?
26
The pressure exerted by 6.0 g of methane gas in a 0.03 m3 vessel at 129oC is (Atomic masses : C = 12.01, H = 1.01 and R = 8.314 J K$$-$$1 mol$$-$$1 )
27
The energy absorbed by each molecule (A2) of a substance is 4.4 $$ \times $$ 10$$-$$19 J and bond energy per molecule is 4.0 $$ \times $$ 10$$-$$19 J. The kinetic energy of the molecule per atom will be
28
Volume occupied by one molecule of water (density = 1 g cm$$-$$3) is
29
If a gas expands at constant temperature, it indicates that
30
In Haber process 30 litres of dihydrogen and 30 litres of dinitrogen were taken for reaction which yielded only 50% of the expected product. What will be the composition of gaseous mixture underthe aforesaid condition in the end ?
31
Van der Waal's real gas, acts as an ideal gas, at which conditions?
32
The beans are cooked earlier in pressure cooker because
33
Which of the following expressions correctly
represents the relationship between the average
molar kinetic energy, KE, of CO and N2 molecules
at the same temperature ?