Chemical Kinetics · Chemistry · NEET
MCQ (Single Correct Answer)
Following data is for a reaction between reactants A and B :
Rate $$\mathrm{mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$$ |
$$\mathrm{[A]}$$ | $$\mathrm{[B]}$$ |
---|---|---|
$$ 2 \times 10^{-3} $$ |
0.1 M | 0.1 M |
$$ 4 \times 10^{-3} $$ |
0.2 M | 0.1 M |
$$ 1.6 \times 10^{-2} $$ |
0.2 M | 0.2 M |
$$ \text { The order of the reaction with respect to } \mathrm{A} \text { and } \mathrm{B} \text {, respectively, are } $$
Which of the following plot represents the variation of $$\ln \mathrm{k}$$ versus $$\frac{1}{\mathrm{~T}}$$ in accordance with Arrhenius equation?
Rate constants of a reaction at $$500 \mathrm{~K}$$ and $$700 \mathrm{~K}$$ are $$0.04 \mathrm{~s}^{-1}$$ and $$0.14 \mathrm{~s}^{-1}$$, respectively; then, activation energy of the reaction is :
(Given: $$\log 3.5=0.5441, \mathrm{R}=8.31 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$)
Activation energy of any chemical reaction can be calculated if one knows the value of
Which plot of $$\ln \mathrm{k}$$ vs $$\frac{1}{\mathrm{~T}}$$ is consistent with Arrhenius equation?
The rate of a reaction quadruples when temperature changes from $$27^{\circ} \mathrm{C}$$ to $$57^{\circ} \mathrm{C}$$. Calculate the energy of activation.
Given $$\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}, \log 4=0.6021$$
For a reaction $$3 \mathrm{~A} \rightarrow 2 \mathrm{~B}$$
The average rate of appearance of $$\mathrm{B}$$ is given by $$\frac{\Delta[B]}{\Delta t}$$. The correct relation between the average rate of appearance of $$\mathrm{B}$$ with the average rate of disappearance of A is given in option :
The correct options for the rate law that corresponds to overall first order reaction is
For a certain reaction, the rate $$=\mathrm{k}[\mathrm{A}]^{2}[\mathrm{~B}]$$, when the initial concentration of A is tripled keeping concentration of $$\mathrm{B}$$ constant, the initial rate would
Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.
Assertion A : A reaction can have zero activation energy.
Reason R : The minimum extra amount of energy absorbed by reactant molecules so that their energy becomes equal to threshold value, is called activation energy.
In the light of the above statements, choose the correct answer from the options given below:
For a chemical reaction
4A + 3B $$\to$$ 6C + 9D
Rate of formation of C is 6 $$\times$$ 10$$-$$2 mol L$$-$$1 s$$-$$1 and rate of disappearance of A is 4 $$\times$$ 10$$-$$2 mol L$$-$$1 s$$-$$1. The rate of reaction and amount of B consumed in interval of 10 seconds, respectively will be :
The given graph is a representation of kinetics of a reaction
The y and x axes for zero and first order reactions, respectively are
For a first order reaction A $$\to$$ Products, initial concentration of A is 0.1 M, which becomes 0.001 M after 5 minutes. Rate constant for the reaction in min$$-$$1 is
[Given R = 8.314 JK$$-$$1mol$$-$$1]
N2(g) + 3H2(g) ⇌ 2NH3(g)
the correct option is :
X2 + Y2 $$ \to $$ 2XY, is given below :
(i) X2 $$ \to $$ X + X (fast)
(ii) X + Y2 $$\rightleftharpoons$$ XY + Y (slow)
(iii) X + Y $$ \to $$ XY (fast)
The overall order of the reaction will be
(R = 8.314 J mol$$-$$1 K$$-$$1)
can be written in three ways.
$${{ - d\left[ {{N_2}{O_5}} \right]} \over {dt}} = k\left[ {{N_2}{O_5}} \right]$$
$${{d\left[ {N{O_2}} \right]} \over {dt}} = k'\left[ {{N_2}{O_5}} \right];\,\,$$ $${{d\left[ {{O_2}} \right]} \over {dt}} = k''\left[ {{N_2}{O_5}} \right]$$
The relationship between k and k' and between k and k'' are
the value of rate of disappearance of N2O5 is given as 6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1. The rate of formation of NO2 and O2 is given respectively as
Run | [A]/mol L$$-$$1 | [B]/mol L$$-$$1 | Initial rate of formation of D/mol L$$-$$1 min$$-$$1 |
---|---|---|---|
I. | 0.1 | 0.1 | 6.0$$ \times $$10$$-$$3 |
II. | 0.3 | 0.2 | 7.2$$ \times $$10$$-$$2 |
III. | 0.3 | 0.4 | 2.88$$ \times $$10$$-$$1 |
IV. | 0.4 | 0.1 | 2.40$$ \times $$10$$-$$2 |
Based on the above data which one of the following is correct?
$${{d\left[ {N{H_3}} \right]} \over {dt}}$$ = 2 $$ \times $$ 10$$-$$4 mol L$$-$$1 s$$-$$1,
the value of $${{ - d\left[ {{H_2}} \right]} \over {dt}}$$ would be
BrO$$_{3(aq)}^ - $$ + 5Br$$_{(aq)}^ - $$ + 6H+ $$ \to $$ 3Br2(l) + 3H2O(l).
The rate of appearance of bromine (Br2) is related to rate of disappearance of bromide ions as
(i) on doubling the initial concentration of A only, the rate of reaction is also doubled and
(ii) on doubling the initial concentration of both A and B, there is a change by a factor of 8 in the rate of the reaction.
The rate of this reaction is given by
CH3COCH3(aq) + Br2(aq) $$ \to $$
CH3COCH2Br(aq) + H+(aq) + Br$$-$$(aq)
These kinetic data were obtained for given reaction concentrations.
Initial concentrations, M | ||||
---|---|---|---|---|
[CH3COCH3 | [Br2] | [H+] | ||
0.30 | 0.05 | 0.05 | ||
0.30 | 0.10 | 0.05 | ||
0.30 | 0.10 | 0.10 | ||
0.40 | 0.05 | 0.20 |
Initial rate, disappearance of Br2, Ms$$-$$1 | ||||||
---|---|---|---|---|---|---|
5.7$$ \times $$10$$-$$5 | ||||||
5.7$$ \times $$10$$-$$5 | ||||||
1.2$$ \times $$10$$-$$4 | ||||||
3.1$$ \times $$10$$-$$4 |
Based on these data, the rate equation is
The temperature at which k1 = k2 is
H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
This reaction is of first order with respect to H2(g) and ICl(g),
following mechanisms were proposed.
Mechanism A :
H2(g) + 2ICl(g) $$ \to $$ 2HCl(g) + I2(g)
Mechanism B :
H2(g) + ICl(g) $$ \to $$ HCl(g) + HI(g) ; slow
HI(g) + ICl(g) $$ \to $$ HCl(g) + I2(g) ; fast
Which of the above mechanism(s) can be consistent with the given information about the reaction?
(log 4 = 0.60, log 5 = 0.69)
The equality relationship between $${{d\left[ {N{H_3}} \right]} \over {dt}}$$ and $$ - {{d\left[ {{H_2}} \right]} \over {dt}}$$ is
The activation energy for reverse reaction
It would be a zero order reaction when
2N2O5 $$ \to $$ 4NO2 + O2 rate and rate constant are 1.02 $$ \times $$ 10$$-$$4 and 3.4 $$ \times $$ 10$$-$$5 sec$$-$$1 respectively, then concentration of N2O5 at that time will be
which of the following relation correctly represents the consumption and formation of products.