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1

### NEET 2013 (Karnataka)

How many gram of cobalt metal will be deposited when a solution of cobalt (II) chloride is electrolyzed with a current of 10 amperes for 109 minutes (1 Faraday = 96,500 C; Atomic mass of Co = 59 u)
A
4.0
B
20.0
C
40.0
D
0.66

## Explanation

W = $${{IEt} \over {96500}}$$

= $${{10 \times 109 \times 60 \times 59} \over {96500}}$$

= 20
2

### NEET 2013

A button cell used in watches function as following.
Zn(s) + Ag2O(s) + H2O(l) $$\rightleftharpoons$$ 2Ag(s) + Zn2+(aq) + 2OH$$-$$(aq)

If half cell potentials are
Zn2+(aq) + 2e$$-$$ $$\to$$ Zn(s);  Eo = $$-$$0.76 V
Ag2O(s) + H2O(l) + 2e$$-$$ $$\to$$ 2Ag(s) + 2OH$$-$$(aq), Eo = 0.34 V

The cell potential will be
A
0.84 V
B
1.34 V
C
1.10 V
D
0.42 V

## Explanation

At anode :Zn2+(aq) + 2e$$-$$ $$\to$$ Zn(s);  Eo = $$-$$0.76 V

At cathode : Ag2O(s) + H2O(l) + 2e$$-$$ $$\to$$ 2Ag(s) + 2OH$$-$$(aq), Eo = 0.34 V

cell = E°cathode – E°anode

= 0.34 – (–0.76) = 1.10 V
3

### NEET 2013

At 25oC molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is 9.54 ohm$$-$$1 cm2 mol$$-$$1 and at infinite dilution its molar conductance is 238 ohm$$-$$1 cm2 mol$$-$$1. The degree of ionisation of ammonium hydroxide at the same concentration and temperature is
A
4.008%
B
40.800%
C
2.080%
D
20.800%

## Explanation

Degree of dissociation($$\alpha$$) = $${{9.54} \over {238}}$$ = 0.04008 = 4.008%
4

### AIPMT 2012 Mains

Molar conductivities $$\left( {\Lambda _m^o} \right)$$ at infinite dilution of NaCl, Hcl and CH3COONa are 126.4, 425.9 and 91.0 S cm2 mol$$-$$1 respectively. $$\left( {\Lambda _m^o} \right)$$ for CH3COOH will be
A
425.5 S cm2 mol$$-$$1
B
180.5 S cm2 mol$$-$$1
C
290.8 S cm2 mol$$-$$1
D
390.5 S cm2 mol$$-$$1

## Explanation

$$\Lambda$$oCH3COOH = $$\Lambda$$oCH3COONa + $$\Lambda$$oHCl - $$\Lambda$$oNaCl

= = 91 + 425.9 – 126.4 = 390.5

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Class 12