1
NEET 2022 Phase 2
MCQ (Single Correct Answer)
+4
-1

Standard electrode potential for the cell with cell reaction

Zn(s) + Cu2+(aq) $$\to$$ Zn2+(aq) + Cu(s)

is 1.1 V. Calculate the standard Gibbs energy change for the cell reaction. (Given F = 96487 C mol$$-$$1)

A
$$-$$200.27 J mol$$-$$1
B
$$-$$200.27 kJ mol$$-$$1
C
$$-$$212.27 kJ mol$$-$$1
D
$$-$$212.27 J mol$$-$$1
2
NEET 2022 Phase 1
MCQ (Single Correct Answer)
+4
-1

At 298 K, the standard electrode potentials of Cu2+ / Cu, Zn2+ / Zn, Fe2+ / Fe and Ag+ / Ag are 0.34 V, $$-$$0.76 V, $$-$$0.44 V V and 0.80 V, respectively.

On the basis of standard electrode potential, predict which of the following reaction cannot occur?

A
CuSO4(aq) + Zn(s) $$\to$$ ZnSO4(aq) + Cu(s)
B
CuSO4(aq) + Fe(s) $$\to$$ FeSO4(aq) + Cu(s)
C
FeSO4(aq) + Zn(s) $$\to$$ ZnSO4(aq) + Fe(s)
D
2CuSO4(aq) + 2Ag(s) $$\to$$ 2Cu(s) + Ag2SO4(aq)
3
NEET 2022 Phase 1
MCQ (Single Correct Answer)
+4
-1

Given below are half cell reactions:

$$MnO_4^ - + 8{H^ + } + 5{e^ - } \to M{n^{2 + }} + 4{H_2}O$$,

$$E_{M{n^{2 + }}/MnO_4^ - }^o = - 1.510\,V$$

$${1 \over 2}{O_2} + 2{H^ + } + 2{e^ - } \to {H_2}O$$

$$E_{{O_2}/{H_2}O}^o = + 1.223\,V$$

Will the permanganate ion, $$MnO_4^ - $$ liberate O2 from water in the presence of an acid?

A
Yes, because $$E_{cell}^o$$ = + 0.287 V
B
No, because $$E_{cell}^o$$ = $$-$$0.287 V
C
Yes, because $$E_{cell}^o$$ = + 2.733 V
D
No, because $$E_{cell}^o$$ = $$-$$ 2.733 V
4
NEET 2022 Phase 1
MCQ (Single Correct Answer)
+4
-1

Find the emf of the cell in which the following reaction takes place at 298 K

Ni(s) + 2Ag+ (0.001 M) $$\to$$ Ni2+ (0.001 M) + 2Ag(s)

(Given that E$$_{cell}^o$$ = 10.5 V, $${{2.303\,RT} \over F} = 0.059$$ at 298 K)

A
1.0385 V
B
1.385 V
C
0.9615 V
D
1.05 V
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