In which of the following equilibria, $$\mathrm{K}_p$$ and $$\mathrm{K}_{\mathrm{c}}$$ are NOT equal?

For the reaction $$2 \mathrm{~A} \rightleftharpoons \mathrm{B}+\mathrm{C}, \mathrm{K}_{\mathrm{c}}=4 \times 10^{-3}$$. At a given time, the composition of reaction mixture is: $$[A]=[B]=[C]=2 \times 10^{-3} \mathrm{M} \text {. }$$ Then, which of the following is correct?

Consider the following reaction in a sealed vessel at equilibrium with concentrations of $$\mathrm{N}_2=3.0 \times 10^{-3} \mathrm{M}, \mathrm{O}_2=4.2 \times 10^{-3} \mathrm{M}$$ and $$\mathrm{NO}=2.8 \times 10^{-3} \mathrm{M}$$.

$$2 \mathrm{NO}_{(\mathrm{g})} \rightleftharpoons \mathrm{N}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})}$$

If $$0.1 \mathrm{~mol} \mathrm{~L} \mathrm{~L}^{-1}$$ of $$\mathrm{NO}_{(\mathrm{g})}$$ is taken in a closed vessel, what will be degree of dissociation ($$\alpha$$) of $$\mathrm{NO}_{(\mathrm{g})}$$ at equilibrium?

For a weak acid HA, the percentage of dissociation is nearly 1% at equilibrium. If the concentration of acid is 0.1 mol L$$^{-1}$$, then the correct option for its K$$_a$$ at the same temperature is :