1
AIPMT 2011 Mains
MCQ (Single Correct Answer)
+4
-1
The rate of the reaction :   2N2O5 $$ \to $$ 4NO2 + O2
can be written in three ways.

$${{ - d\left[ {{N_2}{O_5}} \right]} \over {dt}} = k\left[ {{N_2}{O_5}} \right]$$

$${{d\left[ {N{O_2}} \right]} \over {dt}} = k'\left[ {{N_2}{O_5}} \right];\,\,$$ $${{d\left[ {{O_2}} \right]} \over {dt}} = k''\left[ {{N_2}{O_5}} \right]$$

The relationship between k and k' and between k and k'' are
A
$$k' = 2k ;  k'' = k$$
B
$$k' = 2k ;  k'' = k/2$$
C
$$k' = 2k ;  k'' = 2k$$
D
$$k' = k ;  k'' = k$$
2
AIPMT 2011 Mains
MCQ (Single Correct Answer)
+4
-1
The unit of rate constant for a zero order reaction is
A
mol L$$-$$1 s$$-$$1
B
L mol$$-$$1 s$$-$$1
C
L2 mol$$-$$2 s$$-$$1
D
s$$-$$1
3
AIPMT 2011 Mains
MCQ (Single Correct Answer)
+4
-1
The half-life of a substance in a certain enzyme-catalysed reaction is 138 s. The time required for the concentration of the substance to fall from 1.28 mg L$$-$$1 to 0.04 mg L$$-$$1 is
A
414 s
B
552 s
C
690 s
D
276 s
4
AIPMT 2011 Prelims
MCQ (Single Correct Answer)
+4
-1
Which one of the following statements for the order of a reaction is incorrect?
A
Order can be determined only experimentally.
B
Order is not influenced by stoichiometric coefficient of the reactants.
C
Order of a reaction is sum of power to the concentration terms of reactants to express the rate of reaction.
D
Order of reaction is always whole number.
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