1
AIPMT 2011 Mains
MCQ (Single Correct Answer)
+4
-1
The rate of the reaction :   2N2O5 $$ \to $$ 4NO2 + O2
can be written in three ways.

$${{ - d\left[ {{N_2}{O_5}} \right]} \over {dt}} = k\left[ {{N_2}{O_5}} \right]$$

$${{d\left[ {N{O_2}} \right]} \over {dt}} = k'\left[ {{N_2}{O_5}} \right];\,\,$$ $${{d\left[ {{O_2}} \right]} \over {dt}} = k''\left[ {{N_2}{O_5}} \right]$$

The relationship between k and k' and between k and k'' are
A
$$k' = 2k ;  k'' = k$$
B
$$k' = 2k ;  k'' = k/2$$
C
$$k' = 2k ;  k'' = 2k$$
D
$$k' = k ;  k'' = k$$
2
AIPMT 2011 Prelims
MCQ (Single Correct Answer)
+4
-1
Which one of the following statements for the order of a reaction is incorrect?
A
Order can be determined only experimentally.
B
Order is not influenced by stoichiometric coefficient of the reactants.
C
Order of a reaction is sum of power to the concentration terms of reactants to express the rate of reaction.
D
Order of reaction is always whole number.
3
AIPMT 2010 Mains
MCQ (Single Correct Answer)
+4
-1
The rate of the reaction, 2NO + Cl2 $$ \to $$ 2NOCl is given by the rate equation rate = k[NO]2[Cl2]. The value of the rate constant can be increased by
A
increasing the temperature
B
increasing the concentration of NO
C
increasing the concentration of the Cl2
D
doing all of these.
4
AIPMT 2010 Prelims
MCQ (Single Correct Answer)
+4
-1
For the reaction N2O5(g) $$ \to $$  2NO2(g) + 1/2O2(g)
the value of rate of disappearance of N2O5 is given as 6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1. The rate of formation of NO2 and O2 is given respectively as
A
6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1 and
6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1
B
1.25 $$ \times $$ 10$$-$$2 mol L$$-$$1 s$$-$$1 and
3.125 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1
C
6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1 and
3.125 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1
D
1.25 $$ \times $$ 10$$-$$2 mol L$$-$$1 s$$-$$1 and
6.25 $$ \times $$ 10$$-$$3 mol L$$-$$1 s$$-$$1
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