Which of the following solutions shows positive deviation from Raoult's law?

What is vapour pressure of a solution containing 0.1 mol of non-volatile solute dissolved in 16.2 g of water ? (P$$_1^0=32$$ mm Hg)

What is boiling point of a decimolal aqueous solution of glucose if molal elevation constant for water is 0.52$$^\circ$$C kg mol$$^{-1}$$ ?

What is cryoscopic constant of water if $$5 \mathrm{~g}$$ of glucose in $$100 \mathrm{~g}$$ of water has depression in freezing point $$2.15 \mathrm{~K}$$ ? (Molar mass of glucose $$=180$$ )