Which of the following statements is correct for boiling point of a liquid?

Henry's law constant for $$\mathrm{CH}_3 \mathrm{Br}$$ is $$0.16 \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{bar}^{-1}$$ at $$298 \mathrm{~K}$$. What pressure is required to have solubility of $$0.08 \mathrm{~mol} \mathrm{~L}^{-1}$$ ?

Which of the following solutions does not flow in either direction, when separated by semipermeable membrane? (Molar mass : glucose = 180, urea = 60)

A solution of 6 g of solute in 100 g of water boils at 100.52$$^\circ$$C. The molal elevation constant of water is 0.52 K kg mol$$^{-1}$$. What is molar mass of solute?