Identify false statement form following.

Calculate van't Hoff factor of 0.2 m aquesous solution of an electrolyte if it freezes at $-$0.7 K $\left[\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

Calculate the molar mass of non volatile solute when 5 g of it is dissolved in 50 g solvent, boils at $119.6^{\circ} \mathrm{C}$. $\left[\mathrm{K}_{\mathrm{b}}=3.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right.$, boiling point of pure solvent $=118^{\circ} \mathrm{C}$ ].

Identify an example of solution that consists of solid as solute and liquid as solvent.