Liquid Solution · Chemistry · MHT CET

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MCQ (Single Correct Answer)

1

What type of solution is the iodine in air?

MHT CET 2024 16th May Evening Shift
2

Calculate the relative lowering of vapour pressure if vapour pressure of pure solvent and vapour pressure of solution at $25^{\circ} \mathrm{C}$ are 32 and 30 mm Hg respectively.

MHT CET 2024 16th May Evening Shift
3

Calculate the molality of solution if its depression in freezing point is 0.18 K . $\left[\mathrm{K}_{\mathrm{f}}=1.6 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 16th May Evening Shift
4

Identify the correct statement from following properties.

MHT CET 2024 16th May Morning Shift
5

Calculate van't Hoff factor of 0.15 M solution of electrolyte if it freezes at $-$0.5 K.

$$\left[\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$$

MHT CET 2024 16th May Morning Shift
6

Calculate the relative lowering of vapour pressure of solution containing 46 g of non volatile solute in 162 g of water at $20^{\circ} \mathrm{C}$. [Molar mass of nonvolatile solute $=46 \mathrm{~g} \mathrm{~mol}^{-1}$]

MHT CET 2024 16th May Morning Shift
7

Calculate molar mass of a solute at 300 K if 400 mg of it is dissolved in 300 mL of water exerts osmotic pressure of 0.2 atm .

$$\left(\mathrm{R}=0.0821 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right)$$

MHT CET 2024 15th May Evening Shift
8

What is the vapour pressure of a solution containing 0.1 mol of non volatile solute dissolved in 16.2 g water? $\left(\mathrm{P}_1^0=24 \mathrm{mmHg}\right.$, molar mass of water $18 \mathrm{~g} \mathrm{~mol}^{-1}$ )

MHT CET 2024 15th May Evening Shift
9

What is the expected value of $\Delta T_f$ for $1.25 \mathrm{~m} \mathrm{CaCl}_2$ solution if 1.25 m sucrose solution has $\Delta \mathrm{T}_{\mathrm{f}}$ value x K ?

MHT CET 2024 15th May Morning Shift
10

Calculate Henry's law constant if solubility of gas in water at $25^{\circ} \mathrm{C}$ is $5.14 \times 10^{-4} \mathrm{~mol} \mathrm{dm}^{-3}$ and partial pressure of the gas is 0.75 bar above solution.

MHT CET 2024 15th May Morning Shift
11

A solution of nonvolatile solute is obtained by dissolving 0.8 g in $0.3 \mathrm{dm}^3$ water has osmotic pressure 0.2 atm at 300 K . Calculate the molar mass of solute.

$$\left[\mathrm{R}=0.082 \mathrm{~atm} \mathrm{dm}^3 \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right]$$

MHT CET 2024 15th May Morning Shift
12

In a solution, mole fraction of solute is 0.2 , when lowering in vapour pressure is 10 mm Hg . To get lowering of vapour pressure of 20 mm Hg , mole fraction of solute in solution is

MHT CET 2024 11th May Evening Shift
13

Which of the following solutions will not show flow of solvent in either direction when separated by semipermeable membrane?

MHT CET 2024 11th May Evening Shift
14

The solution containing $18 \mathrm{~g} \mathrm{dm}^{-3}$ glucose (molar mass 180) in water and another containing $6 \mathrm{~g} \mathrm{dm}^{-3}$ of solute A in water boils at same temperature. What is molar mass of A ?

MHT CET 2024 11th May Evening Shift
15

If $P_1$ partial pressure of a gas and $x_1$ is its mole fraction in a mixture, then correct relation between $P_1$ and $x_1$ is

MHT CET 2024 11th May Evening Shift
16

Calculate van't Hoff factor (i) of 0.2 m aqueous solution of an electrolyte if it freezes at $-0.660 \mathrm{~K} .\left(\mathrm{K}_{\mathrm{f}}=1.84 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

MHT CET 2024 11th May Morning Shift
17

Vapour pressure of a pure solvent is 550 mm of Hg . By addition of a non volatile solute it decreases to 510 mm of Hg . Calculate the mole fraction of solute in solution.

MHT CET 2024 11th May Morning Shift
18

Identify the false statement among the following.

MHT CET 2024 11th May Morning Shift
19

Calculate the solubility of a gas having partial pressure 0.15 bar at $25^{\circ} \mathrm{C}$. $\left[\mathrm{K}_{\mathrm{H}}=0.16 \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{bar}^{-1}\right]$

MHT CET 2024 10th May Evening Shift
20

Which from following ionic solids exhibits decrease in its solubility in water with increase of temperature?

MHT CET 2024 10th May Evening Shift
21

Calculate molar mass of nonvolatile solute if a solution containing 0.35 g solute in 100 g water has boiling point elevation 0.01 K $\left[\mathrm{K}_{\mathrm{b}}=0.50 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right.$ ]

MHT CET 2024 10th May Evening Shift
22

0.2 molal aqueous solution of KCl freezes at $-0.680^{\circ} \mathrm{C}$. Calculate van't Hoff factor for this solution. $\left(\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

MHT CET 2024 10th May Morning Shift
23

0.1 molal aqueous solution of glucose boils at $100.16^{\circ} \mathrm{C}$. What is boiling point of 0.5 molal aqueous solution of glucose?

MHT CET 2024 10th May Morning Shift
24

A solution of non volatile solute has boiling point elevation 0.5 K . Calculate molality of solution $\left[\mathrm{K}_{\mathrm{b}}=2.40 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$.

MHT CET 2024 9th May Evening Shift
25

Calculate the molar mass of solute in a solution prepared by dissolving 1 gram in $0.3 \mathrm{~dm}^3$ solvent having osmotic pressure 0.2 atm at 300 K.

$$\left[\mathrm{R}=0.082 \mathrm{~dm}^3 \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right]$$

MHT CET 2024 9th May Evening Shift
26

Assuming complete ionisation, arrange the following solutions in order of increasing osmotic pressure.

a) $0.5 \mathrm{~m} \mathrm{~Li}_2 \mathrm{SO}_4$

b) $\mathrm{0.5 ~m~KCl}$

c) $0.5 \mathrm{~m} \mathrm{~Al}_2\left(\mathrm{SO}_4\right)_3$

d) $0.1 \mathrm{~m~BaCl}_2$

MHT CET 2024 9th May Evening Shift
27

Calculate the cryoscopic constant of solvent when 2.5 gram solute is dissolved in 35 gram solvent lowers its freezing point by 3 K. (molar mass of solute is $117 \mathrm{~g} \mathrm{~mol}^{-1}$)

MHT CET 2024 9th May Morning Shift
28

Identify the reason for the solubility of polar solute in polar solvent from the following.

MHT CET 2024 9th May Morning Shift
29

What is the osmotic pressure of solution prepared by dissolving 3 gram solute in $2 \mathrm{dm}^3$ water at 300 K . (Molar mass of solute $=60 \mathrm{~g} \mathrm{~mol}^{-1}$, $\mathrm{R}=0.0821 \mathrm{dm}^3 \mathrm{~atm} \mathrm{~K} \mathrm{~mol}^{-1})$

MHT CET 2024 9th May Morning Shift
30

Calculate the molar mass of solute when 4 g of it dissolved in $1 \mathrm{dm}^3$ solvent has osmotic pressure 2 atm at 300 K . [R $\left[=0.082 \mathrm{~dm}^3 \mathrm{~atm} \mathrm{~K} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 4th May Evening Shift
31

Calculate $\Delta \mathrm{T}_{\mathrm{f}}$ of aqueous 0.01 m formic acid if van't Hoff factor is 1.1

$$\left[\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~Kg} \mathrm{~mol}^{-1}\right]$$

MHT CET 2024 4th May Evening Shift
32

What is the relation between the vapour pressure of solution, vapour pressure of solvent and its mole fraction in the solution?

MHT CET 2024 4th May Evening Shift
33

Calculate vapour pressure of a solution containing mixture of 2 moles of volatile liquid A and 3 moles of volatile liquid $B$ at room temperature. $\left(\mathrm{P}_{\mathrm{A}}^{\circ}=420, \mathrm{P}_{\mathrm{B}}^{\circ}=610 \mathrm{~mm} \mathrm{~Hg}\right.$)

MHT CET 2024 4th May Morning Shift
34

Calculate the molar mass of non volatile solute when 1 g of it is dissolved in 100 g solvent decreases its freezing point by 0.2 K . $\left[\mathrm{K}_{\mathrm{f}}=1.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 4th May Morning Shift
35

Which of the following solutions on complete dissociation exhibits maximum elevation in boiling point?

MHT CET 2024 4th May Morning Shift
36

The molal elevation boiling point constant for water is $0.513^{\circ} \mathrm{C} \mathrm{Kg} \mathrm{mol}^{-1}$. Calculate boiling point of solution if 0.1 mole of sugar is dissolved in 200 g water?

MHT CET 2024 3rd May Evening Shift
37

What mass of solute (molar mass $58 \mathrm{~g} \mathrm{~mol}^{-1}$) is to be dissolved in $2.5 \mathrm{~dm}^3 \mathrm{~H}_2 \mathrm{O}$ to generate osmotic pressure of 0.245 atm at 300 K ?

$$\left(\mathrm{R}=0.0821 \mathrm{~dm}^3 \text { atm } \mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)$$

MHT CET 2024 3rd May Evening Shift
38

Which of the following equation correctly represents molar mass of a solute by knowing boiling point elevation?

MHT CET 2024 3rd May Evening Shift
39

A solution of non volatile solute has boiling point elevation 1.75 K . Calculate molality of solution $\left[\mathrm{K}_{\mathrm{b}}=3.5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 3rd May Morning Shift
40

Which from the following statements is correct for aqueous solution of $6 \mathrm{~g} \mathrm{~L}^{-1}$ urea and $17 \cdot 12 \mathrm{~g} \mathrm{~L}^{-1}$ of sucrose?

[Molar mass of urea $=60 \mathrm{~g} \mathrm{~mol}^{-1}$

Molar mass of sucrose $=342 \mathrm{~g} \mathrm{~mol}^{-1}$]

MHT CET 2024 3rd May Morning Shift
41

Calculate the molar mass of nonvolatile solute when 1.5 g of it is dissolved in 90 g solvent decreases its freezing point by 0.25 K. $$\left[\mathrm{K}_{\mathrm{f}}=1.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$$

MHT CET 2024 3rd May Morning Shift
42

Identify false statement form following.

MHT CET 2024 2nd May Evening Shift
43

Calculate van't Hoff factor of 0.2 m aquesous solution of an electrolyte if it freezes at $-$0.7 K $\left[\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 2nd May Evening Shift
44

Calculate the molar mass of non volatile solute when 5 g of it is dissolved in 50 g solvent, boils at $119.6^{\circ} \mathrm{C}$. $\left[\mathrm{K}_{\mathrm{b}}=3.2 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right.$, boiling point of pure solvent $=118^{\circ} \mathrm{C}$ ].

MHT CET 2024 2nd May Evening Shift
45

Identify an example of solution that consists of solid as solute and liquid as solvent.

MHT CET 2024 2nd May Morning Shift
46

Calculate the molality of solution of non volatile solute having depression in freezing point 0.93 K and cryoscopic constant of solvent $1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$.

MHT CET 2024 2nd May Morning Shift
47

A solution of non volatile solute is obtained by dissolving 2 g in 50 g benzene. Calculate the vapour pressure of solution if vapour pressure of pure benzene is 640 mmHg at $25^{\circ} \mathrm{C}$. [mol. mass of benzene $=78 \mathrm{~g} \mathrm{~mol}^{-1}$, mol. mass of solute $\left.=64 \mathrm{~g} \mathrm{~mol}^{-1}\right]$

MHT CET 2024 2nd May Morning Shift
48

What is Henry's law constant of a gas if solubility of gas in water at $$25^{\circ} \mathrm{C}$$ is $$0.028 \mathrm{~mol} \mathrm{~dm}^{-3}$$ ?

[Partial pressure of gas $$=0.346 \mathrm{~bar}]$$

MHT CET 2023 14th May Evening Shift
49

A solution of nonvolatile solute is obtained by dissolving $$15 \mathrm{~g}$$ in $$200 \mathrm{~mL}$$ water has depression in freezing point $$0.75 \mathrm{~K}$$. Calculate the molar mass of solute if cryoscopic constant of water is $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$.

MHT CET 2023 14th May Evening Shift
50

What type of following solutions is the gasoline?

MHT CET 2023 14th May Evening Shift
51

Calculate the relative lowering of vapour pressure if the vapour pressure of benzene and vapour pressure of solution of non-volatile solute in benzene are $$640 \mathrm{~mmHg}$$ and $$590 \mathrm{~mmHg}$$ respectively at same temperature.

MHT CET 2023 14th May Morning Shift
52

Calculate the depression in freezing point of solution when $$4 \mathrm{~g}$$ nonvolatile solute of molar mass $$126 \mathrm{~g} \mathrm{~mol}^{-1}$$ dissolved in $$80 \mathrm{~mL}$$ water [Cryoscopic constant of water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$ ]

MHT CET 2023 14th May Morning Shift
53

Which among the following is NOT colligative property?

MHT CET 2023 14th May Morning Shift
54

What is the molality of solution of a non-volatile solute having boiling point elevation $$7.15 \mathrm{~K}$$ and molal elevation constant $$2.75 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$ ?

MHT CET 2023 13th May Evening Shift
55

Which among the following salts exhibits inverse relation between it's solubility and temperature?

MHT CET 2023 13th May Evening Shift
56

If $$0.01 \mathrm{~m}$$ aqueous solution of an electrolyte freezes at $$-0.056 \mathrm{~K}$$. Calculate van't Hoff factor for an electrolyte (cryoscopic constant of water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$ )

MHT CET 2023 13th May Evening Shift
57

Calculate van't Hoff factor of $$\mathrm{K}_2 \mathrm{SO}_4$$ if $$0.1 \mathrm{~m}$$ aqueous solution of $$\mathrm{K}_2 \mathrm{SO}_4$$ freezes at $$-0.43{ }^{\circ} \mathrm{C}$$ and cryoscopic constant of water is $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$.

MHT CET 2023 13th May Morning Shift
58

A solution of $$5.6 \mathrm{~g}$$ non-volatile solute in $$50 \mathrm{~g}$$ solvent has elevation in boiling point $$1.75 \mathrm{~K}$$. What is the molar mass of solute $$\left(\mathrm{K}_{\mathrm{b}}=3 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$$ ?

MHT CET 2023 13th May Morning Shift
59

What is the molal elevation constant if one gram mole of a nonvolatile solute is dissolved in $$1 \mathrm{~kg}$$ of ethyl acetate? $$\left(\Delta \mathrm{T}_{\mathrm{b}}=x \mathrm{~K}\right)$$

MHT CET 2023 13th May Morning Shift
60

If $$0.15 \mathrm{~m}$$ aqueous solution of KCI freezes at $$-0.511^{\circ} \mathrm{C}$$, calculate van't Hoff factor of KCI (cryoscopic constant of water is $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$

MHT CET 2023 12th May Evening Shift
61

What is the solubility of gas in water at $$25^{\circ} \mathrm{C}$$ if partial pressure is 0.346 bar [Henry's law constant is $$[0.159 \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~bar}^{-1}]$$ ?

MHT CET 2023 12th May Evening Shift
62

The partial vapour pressure of any volatile component of a solution is equal to the vapour pressure of the pure component multiplied by its mole fraction in the solution is called

MHT CET 2023 12th May Evening Shift
63

Which among the following solutions has minimum boiling point elevation?

MHT CET 2023 12th May Morning Shift
64

Calculate osmotic pressure of solution of 0.025 mole glucose in $$100 \mathrm{~mL}$$ water at $$300 \mathrm{~K}$$. $$\left[\mathrm{R}=0.082 \mathrm{~atm} \mathrm{dm} \mathrm{mol}^{-1} \mathrm{~K}^{-1}\right]$$

MHT CET 2023 12th May Morning Shift
65

Calculate molality of solution of a nonvolatile solute having boiling point elevation $$1.89 \mathrm{~K}$$ if boiling point elevation constant of solvent is $$3.15 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$.

MHT CET 2023 12th May Morning Shift
66

A solution of nonvolatile solute is obtained by dissolving $$1.5 \mathrm{~g}$$ in $$30 \mathrm{~g}$$ solvent has boiling point elevation $$0.65 \mathrm{~K}$$. Calculate the molal elevation constant if molar mass of solute is $$150 \mathrm{~g} \mathrm{~mol}^{-1}$$.

MHT CET 2023 11th May Evening Shift
67

Identify the FALSE statement about ideal solution from following.

MHT CET 2023 11th May Evening Shift
68

Calculate osmotic pressure of $$0.2 \mathrm{~M}$$ aqueous $$\mathrm{KCl}$$ solution at $$0^{\circ} \mathrm{C}$$ if van't Hoff factor for $$\mathrm{KCl}$$ is 1.83. $$\left[\mathrm{R}=0.082 \mathrm{~dm}^3 \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\right]$$

MHT CET 2023 11th May Evening Shift
69

If $$\mathrm{K}_{\mathrm{b}}$$ denote molal elevation constant of water, then boiling point of an aqueous solution containing $$36 \mathrm{~g}$$ glucose (molar mass $$=180$$ ) per $$\mathrm{dm}^3$$ is:

MHT CET 2023 11th May Morning Shift
70

What is vapour pressure of a solution containing $$1 \mathrm{~mol}$$ of a nonvolatile solute in $$36 \mathrm{~g}$$ of water $$\left(\mathrm{P}_1^0=32 \mathrm{~mm} \mathrm{~Hg}\right)$$ ?

MHT CET 2023 11th May Morning Shift
71

Which among following salts shows decrease in solubility with increase in temperature?

MHT CET 2023 11th May Morning Shift
72

The solubility of a gas in a liquid is directly proportional to the pressure of the gas over the solution. Identify the law for this statement.

MHT CET 2023 10th May Evening Shift
73

What is the solubility of a gas in water at $$25^{\circ} \mathrm{C}$$ if partial pressure is $$0.18 \mathrm{~atm}$$ ?

$$\left(\mathrm{K}_{\mathrm{H}}=0.16 \mathrm{~mol} \mathrm{dm}^{-3} \mathrm{~atm}^{-1}\right)$$

MHT CET 2023 10th May Evening Shift
74

What is osmotic pressure of solution of $$1.7 \mathrm{~g} \mathrm{~CaCl}_2$$ in $$1.25 \mathrm{~dm}^3$$ water at $$300 \mathrm{~K}$$ if van't Hoff factor and molar mass of $$\mathrm{CaCl}_2$$, are 2.47 and $$111 \mathrm{~g} \mathrm{~mol}^{-1}$$ respectively?

$$\left[\mathrm{R}=0.082 \mathrm{~dm}^3 \mathrm{~atm} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}\right]$$

MHT CET 2023 10th May Evening Shift
75

What type of solution is the ethyl alcohol in water?

MHT CET 2023 10th May Morning Shift
76

Find the depression in freezing point of solution when 3.2 gram non volatile solute with molar mass $$128 \mathrm{~gram} \mathrm{~mol}^{-1}$$ is dissolved in $$80 \mathrm{~gram}$$ solvent if cryoscopic constant of solvent is $$4.8 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$.

MHT CET 2023 10th May Morning Shift
77

Which of the following solutions exhibits lowest value of boiling point elevation assuming complete dissociation?

MHT CET 2023 10th May Morning Shift
78

A solution of $$8 \mathrm{~g}$$ of certain organic compound in $$2 ~\mathrm{dm}^3$$ water develops osmotic pressure $$0.6 \mathrm{~atm}$$ at $$300 \mathrm{~K}$$. Calculate the molar mass of compound. [R = 0.082 atm dm$$^3$$ K$$^{-1}$$ mol$$^{-1}$$]

MHT CET 2023 9th May Evening Shift
79

Which from the following compound solutions in water of equal concentration has electrical conductivity nearly same as distilled water?

MHT CET 2023 9th May Evening Shift
80

A solution of nonvolatile solute is obtained by dissolving $$1 \mathrm{~g}$$ in $$100 \mathrm{~g}$$ solvent, decreases its freezing point by $$0.3 \mathrm{~K}$$. Calculate cryoscopic constant of solvent if molar mass of solute is $$60 \mathrm{~g} \mathrm{~mol}^{-1}$$.

MHT CET 2023 9th May Evening Shift
81

Which among the following gases exhibits very low solubility in water at room temperature?

MHT CET 2023 9th May Evening Shift
82

$$0.2 ~\mathrm{M}$$ aqueous solution of glucose has osmotic pressure 4.9 atm at $$300 \mathrm{~K}$$. What is the concentration of glucose if it has osmotic pressure $$1.5 \mathrm{~atm}$$ at same temperature?

MHT CET 2023 9th May Morning Shift
83

A solution of nonvolatile solute is obtained by dissolving $$3.5 \mathrm{~g}$$ in $$100 \mathrm{~g}$$ solvent has boiling point elevation $$0.35 \mathrm{~K}$$. Calculate the molar mass of solute.

(Molal elevation constant $$=2.5 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$ )

MHT CET 2023 9th May Morning Shift
84

Calculate the solubility of a gas in water at $$0.8 \mathrm{~atm}$$ and $$25^{\circ} \mathrm{C}$$.

[Henry's law constant is $$6.85 \times 10^{-4} \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~atm}^{-1}$$ ]

MHT CET 2022 11th August Evening Shift
85

Identify the concentration of the solution from following so that values of ,$$\Delta \mathrm{T}_{\mathrm{f}}$$ and $$\mathrm{K}_{\mathrm{f}}$$ are same.

MHT CET 2022 11th August Evening Shift
86

Calculate the amount of solute dissolved in 160 gram solvent that boils at $$85^{\circ} \mathrm{C}$$, the molar mass of solute is $$120 \mathrm{~g} \mathrm{~mol}^{-1}$$. $$\left(\mathrm{K}_{\mathrm{b}}\right.$$ for solvent $$=2.7^{\circ} \mathrm{C} \mathrm{~kg} \mathrm{~mol}^{-1}$$ and boiling point of solvent $$=76^{\circ} \mathrm{C}$$)

MHT CET 2022 11th August Evening Shift
87

The solution containing $$3 \mathrm{~g}$$ urea (molar mass 60 ) per $$\mathrm{dm}^3$$ of water and another solution containing $$4.5 \mathrm{~g}$$ of solute $$\mathrm{A}$$ per $$\mathrm{dm}^3$$ boils at same temperature, then what is molar mass of $$\mathrm{A}$$ ?

MHT CET 2021 24th September Evening Shift
88

Vapour pressure of solution and of pure solvent are $$\mathrm{P}_1$$ and $$\mathrm{P}_1{ }^0$$ respectively. If $$\frac{P_1}{P_1^0}$$ is 0.15, find the mole fraction of solute.

MHT CET 2021 24th September Evening Shift
89

According to Raoult's law mole fraction of solute in solution in given by formula

MHT CET 2021 24th September Evening Shift
90

What is vapour pressure of solution containing 0.1 mole solute dissolved in $$1.8 \times 10^{-2} \mathrm{~kg} \mathrm{~H}_2 0$$ ? $$(\mathrm{P}_1^0=24 \mathrm{~mm} \mathrm{~Hg})$$

MHT CET 2021 24th September Morning Shift
91

What is vapour pressure of a solution containing $$1 \mathrm{~mol}$$ of a non-volatile solute in $$36 \mathrm{~g}$$ of water? $$(\mathrm{P}_1^0=400 \mathrm{~mm} \mathrm{Hg}$$)

MHT CET 2021 23rd September Evening Shift
92

Which of the following solutions behaves nearly as an ideal solution?

MHT CET 2021 23rd September Evening Shift
93

The solution containing $$6 \mathrm{~g}$$ urea (molar mass 60 ) per $$\mathrm{dm}^3$$ of water and another solution containing $$9 \mathrm{~g}$$ of solute $$\mathrm{A}$$ per $$\mathrm{dm}^3$$ water freezes at same temperature. What is molar mass of $$\mathrm{A}$$ ?

MHT CET 2021 23rd September Evening Shift
94

What is vapour pressure of solution containing $$1.8 \mathrm{~g}$$ glucose in $$16.2 \mathrm{~g}$$ water?

($$\mathrm{P}_1^0=24 \mathrm{~mm} \mathrm{Hg}$$ and Molar mass of glucose $$=180 \mathrm{~g} \mathrm{~mol}^{-1}$$)

MHT CET 2021 23th September Morning Shift
95

What is the freezing point of 1 molal aqueous solution of a non volatile solute?

($$\mathrm{K}_{\mathrm{f}}=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$ ($$\mathrm{T}_{\mathrm{f}}^0$$ for water $$=0^{\circ} \mathrm{C})$$

MHT CET 2021 23th September Morning Shift
96

Air is an example of a solution of

MHT CET 2021 23th September Morning Shift
97

5 g sucrose (molar mass = 342) is dissolved in 100 g of solvent, decreases the freezing point by 2.15 K. What is cryoscopic constant of solvent?

MHT CET 2021 22th September Evening Shift
98

What is Henry's law constant if solubility of a gas in water at $$298 \mathrm{~K}$$ and 1 bar pressure is $$7\times10^{-4} \mathrm{~mol} \mathrm{~L}^{-1}$$ ?

MHT CET 2021 22th September Evening Shift
99
Which of the following formulae is used to obtain depression in freezing point?

MHT CET 2021 22th September Evening Shift
100

The vapour pressure of a solvent decreases by 2.5 mm Hg by adding a solute. What is the mole fraction of solute? (Vapour pressure of pure solvent is 250 mm Hg)

MHT CET 2021 22th September Morning Shift
101

Molal depression constant for a liquid is $$2.77^{\circ} \mathrm{C} ~\mathrm{kg} ~\mathrm{mol}^{-1}$$, in Kelvin scale it's value is

MHT CET 2021 22th September Morning Shift
102

If 6 g of solute dissolved in 100 g of water lowers the freezing point by 0.93 K. What is molar mass of solute? (K$$_\mathrm{f}$$ = 1.86 K kg mol$$^{-1}$$)

MHT CET 2021 22th September Morning Shift
103

What is vapour pressure of a solution when $$2 \mathrm{~mol}$$ of a non-volatile solute are dissolved in $$20 \mathrm{~mol}$$ of water? $$\left(\mathrm{P}_1^0=32 \mathrm{~mm} \mathrm{Hg}\right)$$

MHT CET 2021 21th September Evening Shift
104

In which of the following salts, the solubility increases appreciably with increase in temperature?

MHT CET 2021 21th September Evening Shift
105

What is the boiling point of 0.5 molal aqueous solution of sucrose if 0.1 molal aqueous solution of glucose boils at 100.16$$^\circ$$C?

MHT CET 2021 21th September Evening Shift
106

Which of the following solutions shows positive deviation from Raoult's law?

MHT CET 2021 21th September Morning Shift
107

What is vapour pressure of a solution containing 0.1 mol of non-volatile solute dissolved in 16.2 g of water ? (P$$_1^0=32$$ mm Hg)

MHT CET 2021 21th September Morning Shift
108

What is boiling point of a decimolal aqueous solution of glucose if molal elevation constant for water is 0.52$$^\circ$$C kg mol$$^{-1}$$ ?

MHT CET 2021 21th September Morning Shift
109

What is cryoscopic constant of water if $$5 \mathrm{~g}$$ of glucose in $$100 \mathrm{~g}$$ of water has depression in freezing point $$2.15 \mathrm{~K}$$ ? (Molar mass of glucose $$=180$$ )

MHT CET 2021 20th September Evening Shift
110

Which of the following statements is correct for boiling point of a liquid?

MHT CET 2021 20th September Evening Shift
111

Henry's law constant for $$\mathrm{CH}_3 \mathrm{Br}$$ is $$0.16 \mathrm{~mol} \mathrm{~L}^{-1} \mathrm{bar}^{-1}$$ at $$298 \mathrm{~K}$$. What pressure is required to have solubility of $$0.08 \mathrm{~mol} \mathrm{~L}^{-1}$$ ?

MHT CET 2021 20th September Evening Shift
112

Which of the following solutions does not flow in either direction, when separated by semipermeable membrane? (Molar mass : glucose = 180, urea = 60)

MHT CET 2021 20th September Morning Shift
113

A solution of 6 g of solute in 100 g of water boils at 100.52$$^\circ$$C. The molal elevation constant of water is 0.52 K kg mol$$^{-1}$$. What is molar mass of solute?

MHT CET 2021 20th September Morning Shift
114

If vapour pressure of pure solvent and solution are 240 and 216 mm Hg respectively then mole fraction of solvent in solution is

MHT CET 2021 20th September Morning Shift
115

The vapour pressure of solvent decreases by 10 mm Hg , if mole fraction of non-volatile solute is 0.2 . Calculate vapour pressure of solvent.

MHT CET 2020 19th October Evening Shift
116

Which of the following $0-10 \mathrm{~m}$ aqueous solutions will have maximum $\Delta T_f$ value?

MHT CET 2020 19th October Evening Shift
117

If boiling point of urea solution is $100.18^{\circ} \mathrm{C}$ and $K_b$ for water is $0.512 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$, molality of solution is (Boiling point of water $=100^{\circ} \mathrm{C}$)

MHT CET 2020 19th October Evening Shift
118

What is osmotic pressure of a semi molar solution at $$27^{\circ} \mathrm{C}$$ ? $$(R=0.082)$$

MHT CET 2020 16th October Evening Shift
119

Solutions $$A, B, C$$ and $$D$$ are respectively 0.2 M urea, $$0.10 \mathrm{~M} \mathrm{~NaCl}, 0.05 \mathrm{~M} \mathrm{~BaCl}_2$$ and 0.05 M $$\mathrm{AlCl}_3$$. All solutions are isotonic with each other except

MHT CET 2020 16th October Evening Shift
120

A solution has an osmotic pressure of '$$x$$' $$\mathrm{kPa}$$ at $$300 \mathrm{~K}$$ having 1 mole of solute in $$10.5 \mathrm{~m}^3$$ of solution. If it's osmotic pressure is reduced to $$\left(\frac{1}{10}\right)$$th of it's initial value, what is the new volume of solution?

MHT CET 2020 16th October Morning Shift
121

If a centimolal aqueous solution of K$$_3$$[Fe(CN)$$_6$$] has degree of dissociation 0.78. What is the value of van't Hoff factor?

MHT CET 2020 16th October Morning Shift
122

The elevation in boiling point of 0.25 molal aqueous solution of a substance is $\left(K_o=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

MHT CET 2019 3rd May Morning Shift
123

Which among the following salts, solubility decreases with increase in temperature?

MHT CET 2019 3rd May Morning Shift
124

18 gram glucose (Molar mass $=180$ ) is dissolved in 100 ml of water at 300 K . If $R=3$ $0.0821 \mathrm{~L}{-\mathrm{a t m}} \mathrm{~mol}^{-1} \mathrm{~K}^{-1}$ what is the osmotic pressure of solution?

MHT CET 2019 3rd May Morning Shift
125

Relationship between van't Hoff's factor (i) and degree of dissociation $(\alpha)$ is

MHT CET 2019 2nd May Evening Shift
126

9 gram anhydrous oxalic acid (mol. $\mathrm{wt} .=90)$ was dissolved in 9.9 moles of water. If vapour pressure of pure water is $p_1^{\circ}$ the vapour pressure of solution is

MHT CET 2019 2nd May Evening Shift
127

Which of the following sets of solutions of urea ( mol . mass $60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) and sucrose ( mol . mass $342 \mathrm{~g} \mathrm{~mol}^{-1}$ ) is isotonic?

MHT CET 2019 2nd May Evening Shift
128

Which of the following sets of components form homogeneous mixture?

MHT CET 2019 2nd May Morning Shift
129

Calculate van't Hoff-factor for 0.2 m aqueous solution of KCl which freezes at $-0.680^{\circ} \mathrm{C}$. $\left(K_f=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right)$

MHT CET 2019 2nd May Morning Shift
130

' $K$ is Henry's constant and has the unit

MHT CET 2019 2nd May Morning Shift
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