Aldehyde and Ketone · Chemistry · MHT CET

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MCQ (Single Correct Answer)

1

Identify name of reaction when aldehyde or ketone react with $\mathrm{Zn}-\mathrm{Hg} /$ conc. HCl to give alkane.

MHT CET 2024 16th May Evening Shift
2

Identify reactant 'A' in following reaction.

MHT CET 2024 15th May Evening Shift Chemistry - Aldehyde and Ketone Question 3 English

MHT CET 2024 15th May Evening Shift
3

Which of the following is a simple ketone?

MHT CET 2024 15th May Evening Shift
4

Aldol condensation reaction is

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5

Identify the reagent ' R ' used in the following reaction.

Ketone $\xrightarrow{\mathbf{R}}$ Semicarbazone

MHT CET 2024 15th May Morning Shift
6

Identify the product in following reaction. Pent -3-enenitrile $\xrightarrow[\mathrm{H}_3 \mathrm{O}^{+}]{\mathrm{AlH}(\mathrm{B}-\mathrm{B})_2}$ product

MHT CET 2024 11th May Evening Shift
7

Identify product 'B' in following reaction

MHT CET 2024 11th May Evening Shift Chemistry - Aldehyde and Ketone Question 6 English

MHT CET 2024 11th May Evening Shift
8

Identify the product obtained when excess of benzoyl chloride is treated with dimethyl cadmium.

MHT CET 2024 11th May Morning Shift
9

Identify an aldehyde used in margarine and in food for its buttery odour.

MHT CET 2024 10th May Evening Shift
10

What type of following compounds is obtained in first step of Wolf-Kishner reduction of carbonyl compounds?

MHT CET 2024 9th May Evening Shift
11

What is the product obtained in the reaction?

$\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_2-\mathrm{CHO} \xrightarrow[\text { (i) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \mathrm{LAH}_4}$ product

MHT CET 2024 9th May Morning Shift
12

Which of the following compounds is used to convert acetaldehyde into acetaldehyde cynanohydrin?

MHT CET 2024 9th May Morning Shift
13

Identify the test from following so that aldehyde when boiled with ammoniacal silver nitrate solution deposts silver.

MHT CET 2024 9th May Morning Shift
14

What is the general molecular formula of aldehydes?

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15

Which of the following is Stephen reaction?

MHT CET 2024 4th May Morning Shift
16

Which of the following compounds when treated with ammoniacal silver nitrate exhibits silver mirror test?

MHT CET 2024 4th May Morning Shift
17

What type of product is obtained when formaldehyde reacts with $\mathrm{CH}_3 \mathrm{MgBr}$ in dry ether?

MHT CET 2024 3rd May Evening Shift
18

Identify the product ' B ' in the following sequence of reactions. Propanone $\xrightarrow{\mathrm{B_a}(\mathrm{OH})_2} A \xrightarrow[-\mathrm{H}_2 \mathrm{O}]{\Delta} B$

MHT CET 2024 3rd May Morning Shift
19

Identify the reagent ' R ' used in the following reaction. Benzoyl chloride $$ \to $$ Benzaldehyde

MHT CET 2024 3rd May Morning Shift
20

Which of the following compounds does not undergo haloform reaction?

MHT CET 2024 3rd May Morning Shift
21

Identify the product 'B' in the following reaction.

Ethylphenyl ketone $\xrightarrow{\mathrm{H}_2 \mathrm{~N}-\mathrm{NH}_2}$ A $\xrightarrow[\Delta]{\mathrm{KOH}, \mathrm{HO}\left(\mathrm{CH}_2\right)_2 \mathrm{OH}}$ B

MHT CET 2024 2nd May Evening Shift
22

Which of the following reactions represents Clemmensen reduction?

MHT CET 2024 2nd May Evening Shift
23

Identify the product ' B ' in the following sequence of reactions.

$$\mathrm{CH}_3 \mathrm{MgBr} \xrightarrow{\mathrm{CdCl}_2} \mathrm{~A} \xrightarrow{\mathrm{CH}_3 \mathrm{COCl}_1} \mathrm{~B}$$

MHT CET 2024 2nd May Morning Shift
24

Identify the compound '$$\mathrm{A}$$' in the following sequence of reactions.

$$\text { A } \xrightarrow[\text { Dryether }]{\mathrm{C}_2 \mathrm{H}_3 \mathrm{MgBr}} \mathrm{B} \xrightarrow{\mathrm{H}_3 \mathrm{O}^{+}} \text {3-Methylpentan-3-0l }$$

MHT CET 2023 14th May Evening Shift
25

Which of the following is Clemmensen reduction?

MHT CET 2023 14th May Evening Shift
26

Identify substrate 'A' in the following reaction.

2nA $$\mathrm{\buildrel {Dimethyl\,cadmium} \over \longrightarrow}$$ 2n Propanone + n Cadmium chloride

MHT CET 2023 14th May Evening Shift
27

Identify the reaction in which carbonyl group of aldehydes and ketones is reduced to methylene group on treatment with hydrazine followed by heating with sodium hydroxide in ethylene glycol.

MHT CET 2023 14th May Morning Shift
28

Identify the product '$$\mathrm{B}$$' in the following reaction. Toluene $$\xrightarrow[\mathrm{CS}_2]{\text { Chromylchloride }} \mathrm{A} \xrightarrow{\mathrm{H}_3 \mathrm{O}^{+}}\mathrm{B}$$

MHT CET 2023 14th May Morning Shift
29

Which among the following is a simple ketone?

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30

Which from following compounds is obtained when toluene is treated with $$\mathrm{CrO}_2 \mathrm{Cl}_2$$ in presence of $$\mathrm{CS}_2$$ followed by acid hydrolysis?

MHT CET 2023 13th May Evening Shift
31

Which of the following is NOT prepared by the action of Grignard's reagent on methanal?

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32

Which following reagent is used in Etard reaction?

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33

Which of the following compounds is obtained by Rosenmund reduction of benzoyl chloride?

MHT CET 2023 12th May Evening Shift
34

Identify product '$$B$$' in following sequence of reactions.

2n Propanone $$\mathrm{\buildrel {Ba{{(OH)}_2}} \over \longrightarrow}$$ A $$\mathrm{\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{ - {H_2}O}^\Delta }}$$ nB

MHT CET 2023 12th May Morning Shift
35

Which of the following reactions is Rosenmund reduction?

MHT CET 2023 12th May Morning Shift
36

What type of following phenomena does the Cannizzaro reaction exhibit?

MHT CET 2023 12th May Morning Shift
37

Identify the reagent 'R' used in the following reaction.

MHT CET 2023 11th May Evening Shift Chemistry - Aldehyde and Ketone Question 66 English

MHT CET 2023 11th May Evening Shift
38

Identify the products of following reaction:

MHT CET 2023 11th May Morning Shift Chemistry - Aldehyde and Ketone Question 65 English

MHT CET 2023 11th May Morning Shift
39

Which of the following reagents is used in Gatterman-Koch formylation of arene?

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40

Which among the following compounds is hemiacetal?

MHT CET 2023 10th May Morning Shift
41

Which among the following colours is obtained in Schiff test of aldehydes?

MHT CET 2023 10th May Morning Shift
42

Identify ketone from the following.

MHT CET 2023 10th May Morning Shift
43

Which of the following on reaction with ammoniacal silver nitrate forms silver precipitate?

MHT CET 2023 9th May Evening Shift
44

Identify the product 'B' in following reaction.

Ethyl phenyl ketone $$\mathrm{\buildrel {{H_2}N - N{H_2}} \over \longrightarrow}$$ A $$\mathrm{\mathrel{\mathop{\kern0pt\longrightarrow} \limits_\Delta ^{KOH,HO - {{(C{H_2})}_2} - OH}}}$$

MHT CET 2023 9th May Morning Shift
45

What type of reaction is the formation of aldol from aldehyde?

MHT CET 2023 9th May Morning Shift
46

What is the product formed when cumene is air oxidised in presence of Co-naphthenate and further treated with dilute acid?

MHT CET 2022 11th August Evening Shift
47

Identify compound $$\mathrm{A}$$ in following reaction

Benzene + Ozone (excess) $$\rightarrow$$ Benzenetriozonide $$\xrightarrow{\mathrm{A}}$$ Glyoxal

MHT CET 2022 11th August Evening Shift
48

Which of the following aldehydes is less reactive towards nucleophilic addition reaction?

MHT CET 2021 24th September Evening Shift
49

Cannizzaro reaction is an example of

MHT CET 2021 24th September Evening Shift
50

Which of the following reaction is an example of Rosenmund reduction?

MHT CET 2021 24th September Morning Shift
51

To obtain 3-methylbutan-2-ol from acetaldehyde, the Grignard's reagent used is

MHT CET 2021 24th September Morning Shift
52

Which of the following aldehyde has buttery odour?

MHT CET 2021 24th September Morning Shift
53

Identify product B in following reaction.

Propanone $$\xrightarrow{\mathrm{Ba}(\mathrm{OH})_2} \mathrm{~A} \xrightarrow[-\mathrm{H}_2 \mathrm{O}]{\Delta} \mathrm{B}$$

MHT CET 2021 23rd September Evening Shift
54

Identify compound A from following reaction.

$$\mathrm{A}+\mathrm{C}_2 \mathrm{H}_5 \mathrm{MgBr} \xrightarrow[\text { ety }]{\text { drer }} \mathrm{B} \xrightarrow{\mathrm{H}_3 \mathrm{O}^{+}} \text {3-methylpentan-3-ol }$$

MHT CET 2021 23rd September Evening Shift
55

Identify product $$\mathrm{C}$$ in following conversion.

m - Hydroxy Benzaldehyde $$ \xrightarrow[\text { [Protection of }-\mathrm{OH} \text { group] }]{\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Cl}} $$ $$ \mathrm{A} \xrightarrow{[\mathrm{O}]} \mathrm{B} $$ $$ \xrightarrow[\text { [deprotection of }-\mathrm{OH} \text { group] }]{} $$ C

MHT CET 2021 23th September Morning Shift
56

Identify the reagent used in following conversion.

Pent -3 -enenitrile $$\xrightarrow{\mathrm{A}}$$ pent -3 -enal

MHT CET 2021 23th September Morning Shift
57

What is the product formed when side chain chlorination of toluene is carried out followed by acid hydrolysis at $$373 \mathrm{~K}$$ ?

MHT CET 2021 23th September Morning Shift
58

Identify the product '$$B$$' in following reaction.

$$2 \mathrm{CH}_3 \mathrm{CHO} \xrightarrow{\text { dil. } \mathrm{NaOH}} \mathrm{A} \xrightarrow[-\mathrm{H}_2 \mathrm{O}]{\Delta} \mathrm{B}$$

MHT CET 2021 22th September Evening Shift
59

Identify 'A' in following reaction.

A $$\mathrm{\buildrel {Dimethyl\,cadmium} \over \longrightarrow}$$ propanone + cadmium chloride

MHT CET 2021 22th September Morning Shift
60

Which of the following reagents is used in the reaction shown below?

Benzoyl chloride $$\stackrel{?}{\longrightarrow}$$ Benzaldehyde

MHT CET 2021 21th September Evening Shift
61

Identify the name of following reaction.

Toluene + chromyl chloride $$\stackrel{\mathrm{CS}_2}{\longrightarrow}$$ complex $$\stackrel{\mathrm{H}_3 \mathrm{O}^{+}}{\longrightarrow}$$ Benzaldehyde

MHT CET 2021 21th September Evening Shift
62

Identify the product formed when benzoyl chloride is reduced by hydrogen using palladium catalyst poisoned with barium sulphate?

MHT CET 2021 21th September Evening Shift
63

Identify the reagent used in following conversion.

MHT CET 2021 21th September Morning Shift Chemistry - Aldehyde and Ketone Question 75 English

MHT CET 2021 21th September Morning Shift
64

Which from following reactions converts carbonyl group of aldehydes and ketones to methylene group on treatment with zinc amalgam and concentrated $$\mathrm{HCl}$$ ?

MHT CET 2021 21th September Morning Shift
65

Which among the following compounds has highest boiling point?

MHT CET 2021 20th September Evening Shift
66

Identify the product formed in the following reaction,

$$\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_2-\mathrm{CHO} \mathrm{\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{(ii)\,{H_2}{O^ + }}^{(i)\,LiAl{H_4}}}} \text {Products }$$

MHT CET 2021 20th September Evening Shift
67

When alcoholic solution of an organic compound is treated with few drops of Schiff's reagent, pink colour appears. This confirms the presence of group

MHT CET 2021 20th September Morning Shift
68

Which of the following compounds on reaction with Grignard reagent followed by hydrolysis forms secondary alcohol?

MHT CET 2021 20th September Morning Shift
69

The reagent used in Gatterman-Koch formylation of arene is

MHT CET 2021 20th September Morning Shift
70

Which of the following compounds on reaction with ammonical silver nitrate solution forms precipitate of silver?

MHT CET 2021 20th September Morning Shift
71

Identify $A$ in the following reaction.

$$A+\mathrm{CH}_3 \mathrm{MgBr} \xrightarrow{\text { Ether }} \text { complex }\xrightarrow{\mathrm{H}_3 \mathrm{O}^{+}}\left(\mathrm{CH}_3\right)_3 \mathrm{C}-\mathrm{OH}$$

MHT CET 2020 19th October Evening Shift
72

Which of the following is a Stephen reaction?

MHT CET 2020 19th October Evening Shift
73

Which of the following compound is highly reactive towards HCN?

MHT CET 2020 19th October Evening Shift
74

Which of the following compounds reacts with ammonia to form urotropine?

MHT CET 2020 19th October Evening Shift
75

Number of oxygen atoms present in salicylaldehyde are

MHT CET 2020 16th October Evening Shift
76

An acylchloride is hydrogenated over catalyst palladium on barium sulphate to form an aldehyde. This reaction is called as

MHT CET 2020 16th October Evening Shift
77

Propane nitrile on reaction with ethyl magnesium iodide in presence of dry ether gives complex. This imine complex on acid hydrolysis forms

MHT CET 2020 16th October Evening Shift
78

Which of the following alcohols needs acidic $$\mathrm{KMnO}_4$$ to convert it into aldehyde or ketone?

MHT CET 2020 16th October Morning Shift
79

Which of the following statements is true for carbonyl group?

MHT CET 2020 16th October Morning Shift
80

Which of the following does not give yellow solid on treatment with sodium hypoiodite?

MHT CET 2019 3rd May Morning Shift
81

Mandelonitrile is obtained by the reaction between hydrogen cyanide and

MHT CET 2019 2nd May Morning Shift
82

In the reaction, $\mathrm{C}_6 \mathrm{H}_5 \mathrm{COCH}_3 \xrightarrow[\mathrm{Zn}-\mathrm{Hg} / \text { conc. } \mathrm{HCl}]{[\mathrm{H}]} X,X$ is

MHT CET 2019 2nd May Morning Shift
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