Thermodynamics · Chemistry · MHT CET

The enthalpy of vaporisation of a liquid is $30 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and entropy of vaporisation is $75 \mathrm{JK}^{-1} \mathrm{~mol}^{-1...

Find work done on 2 mole of an ideal gas at $27^{\circ} \mathrm{C}$ if it is compressed reversibly and isothermally from $5.05 \times 10^6 \mathrm{Nm}...

A system performs mechanical work equal to 15 kJ and looses 2 kJ of heat to surrounding. What is the change in internal energy of a system?

Find the constant external pressure required to expand a gas from 2.5 L to 4.5 L if amount of work done is 500 J at 298 K ?

In a particular reaction ' x ' kJ of heat is released by the system and ' y ' kJ of work done is done on the system. What is internal energy change?...

Calculate the value of $\Delta G$ for the following reaction. $\mathrm{N}_2 \mathrm{O}_{4(\mathrm{~g})} \longrightarrow 2 \mathrm{NO}_{2(\mathrm{~g})}...

Under similar conditions enthalpy of freezing is exactly opposite to

100 ml of $\mathrm{H}_{2(\mathrm{~g})}$ and 100 ml of $\mathrm{Cl}_{2(\mathrm{~g})}$ were allowed to react at 1 bar pressure as $$\mathrm{H}_{2(\mathr...

Identify the process from following such that volume of system remains constant.

Two moles of an ideal gas are compressed isothermally and reversibly from 40 L to 20 L at 300 K . What is the work done? $\left(\mathrm{R}=8.314 \math...

Calculate the enthalpy change when 12 g carbon react with sufficient hydrogen to form methane. If enthalpy of formation of methane is $-75 \mathrm{~kJ...

Which among the following pair of properties are intensive?

2 moles of an ideal gas expands isothermally from $5 \mathrm{dm}^3$ to $10 \mathrm{dm}^3$ at a constant external pressure of 1.5 bar. Calculate work d...

An ideal gas expands against constant external pressure of 2 bar from 5 lit to 8 lit and absorbs 10 kJ of heat. What is $\Delta \mathrm{U}$ of the sys...

For an ideal gas, the heat of reaction at constant pressure and heat of reaction at constant volume are related by equation _________

For the reaction $\mathrm{CH}_{4(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})} \longrightarrow \mathrm{C}_2 \mathrm{H}_{6(\mathrm{~g})}$ $\mathrm{K}_{\mat...

A gas expands isothermally against a constant external pressure of 1 bar from 10 dm$^3$ to 20 dm$^3$ by absorbing 800 J of heat from surrounding. Calc...

Which of the following equations indicates increase in entropy?

Which from following statements is true about internal energy?

2 moles of an ideal gas are expanded isothermally and reversibly from 20 L to 40 L at 300 K . Calculate work done. ( $\mathrm{R}=8.314 \mathrm{~J} \ma...

10 g each of $\mathrm{NH}_3, \mathrm{~N}_2, \mathrm{Cl}_2$ and $\mathrm{H}_2 \mathrm{~S}$ are expanded isothermally and reversibly at same temperature...

Identify the factor from following on which heat of reaction does not depend.

For the reaction, $$2 \mathrm{H}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow 2 \mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}, \Delta \mathrm...

For the reaction, $$\mathrm{C}_3 \mathrm{H}_{8(\mathrm{~g})}+5 \mathrm{O}_{2(\mathrm{~g})} \longrightarrow 3 \mathrm{CO}_{2(\mathrm{~g})}+4 \mathrm{H}...

What is change in internal energy of the system when work done by the system is 150 J and system release 300 J of heat?

Two moles of an ideal gas is expanded isothermally from a volume of $300 \mathrm{~cm}^3$ to 2.5 $\mathrm{dm}^3$ at 298 K against a constant pressure a...

Calculate heat required to convert 9 g of liquid water to water vapours from following equations. $$\begin{aligned} & \mathrm{H}_{2(\mathrm{~g})}+\fra...

One mole of a gas occupying 3 L volume is expanded against a constant external pressure of 1 bar to a volume of 15 L . Calculate work done by the syst...

Which from the following defines enthalpy of a system?

Which of the following symbols represent heat of reaction at constant volume?

Calculate the entropy change for melting 1 g ice at $0^{\circ} \mathrm{C}$ in $\mathrm{Jg}^{-1} \mathrm{~K}^{-1}$ if heat of fusion of ice at $0^{\cir...

Which of the following set of properties is correct when one mole of a gas is heated keeping volume constant by increasing temperature and supplying 5...

Find value of Q from following equations. (i) $\mathrm{C}_{(\mathrm{s})}+\mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{CO}_{2(\mathrm{~g})} \Del...

Which of the following statements is appropriate as per first law of thermodynamics?

 Given that $$\mathrm{C}_{(\mathrm{g})}+4 \mathrm{H}_{(\mathrm{g})} \longrightarrow \mathrm{CH}_{4(\mathrm{g})} \Delta \mathrm{H}^{\circ}=-1665 \mathr...

If bond formation energy of $\mathrm{H}-\mathrm{H}$ bond is $-433 \mathrm{~kJ} \mathrm{~mol}^{-1}$ find the bond dissociation energy for 0.5 mole $H_{...

What is the value of standard enthalpy of formation of dihydrogen?

Calculate Gibbs energy change for a reaction having $\Delta \mathrm{H}=31400 \mathrm{~J}, \Delta \mathrm{~S}=32 \mathrm{~J} \mathrm{~K}^{-1}$ at $1000...

If 100 L gas is enclosed in a cylinder, absorbs 302.6 J of heat and expands to 200 L against constant external pressure of 2 atm . Calculate internal ...

Which of the following is true for the value of $\Delta \mathrm{H}-\Delta \mathrm{U}$ at constant volume?

Calculate enthalpy change for following reaction. $$\mathrm{H}_2 \mathrm{C}=\mathrm{CH}_{2(\mathrm{~g})}+\mathrm{H}_{2(\mathrm{~g})} \longrightarrow \...

Which among the following is NOT an intensive property?

In a process 605 J heat is absorbed by the system and 380 J work is done by the system on surrounding. What is the value of $\Delta$U?

A gas absorbs certain amount of heat and expands by $200 \mathrm{~cm}^3$ against a constant external pressure of $2 \times 10^5 \mathrm{Nm}^{-2}$. Wha...

For a reaction $$\mathrm{A}+\mathrm{B} \rightarrow$$ products $$\Delta \mathrm{H}$$ is $$-84.2 \mathrm{~kJ}$$ and $$\Delta \mathrm{S}$$ is $$-200 \mat...

Which from following thermodynamic properties is a path function?

Calculate the PV type of work for the following reaction at 1 bar pressure. $$\mathrm{\mathop {{C_3}{H_{6(g)}}}\limits_{(150\,mL)} + \mathop {HC{l_{(...

If enthalpy change for following reaction at $$300 \mathrm{~K}$$ is $$+7 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ find the entropy change of surrounding? $$\...

Calculate $$\Delta \mathrm{H}$$ for following reaction, at $$25{ }^{\circ} \mathrm{C}$$. $$\mathrm{NH}_2 \mathrm{CN}_{(\mathrm{g})}+\frac{3}{2} \mathr...

Identify false statement regarding isothermal process from following.

Two moles of an ideal gas expand freely and isothermally from $$5 \mathrm{~dm}^3$$ to $$50 \mathrm{~dm}^3$$. What is the value of $$\Delta H$$ ?...

Which among the following is intensive and extensive properties respectively?

An ideal gas absorbs $$210 \mathrm{~J}$$ of heat and undergoes expansion from $$3 \mathrm{~L}$$ to $$6 \mathrm{~L}$$ against a constant external press...

Which of the following processes exhibits increase in internal energy?

One mole of an ideal gas performs $$900 \mathrm{~J}$$ of work on surrounding. If internal energy increases by $$625 \mathrm{~J}$$, find the value of $...

Which of the following temperature values in Fahrenheit $$\left({ }^{\circ} \mathrm{F}\right)$$ is equal to $$50^{\circ} \mathrm{C}$$ ?

Calculate the work done in the following reaction at $$300 \mathrm{~K}$$ and at constant pressure. $$\left(\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-...

Which among the following is NOT the feature of reversible process?

A gas absorbs $$150 \mathrm{~J}$$ heat and expands by $$300 \mathrm{~cm}^3$$ against a constant external pressure $$2 \times 10^5 \mathrm{~N} \mathrm{...

Equal masses in grams of $$\mathrm{H}_2, \mathrm{~N}_2, \mathrm{Cl}_2$$, and $$\mathrm{O}_2$$, are enclosed in cylinders separately. If these gases ex...

If lattice enthalpy and hydration enthalpy of $$\mathrm{KCl}$$ are $$699 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and $$-681.8 \mathrm{~kJ} \mathrm{~mol}^{-1...

For reaction, $$\mathrm{CO}_{(\mathrm{g})}+\frac{1}{2} \mathrm{O}_{2(\mathrm{~g})} \longrightarrow \mathrm{CO}_{2(\mathrm{~g})}$$ Which of the followi...

Calculate amount of methane formed by liberation of $$149.6 \mathrm{~kJ}$$ of heat using following equation. $$\mathrm{C}_{(\mathrm{s})}+2 \mathrm{H}_...

Calculate $$\Delta \mathrm{S}_{\text {total }}$$ for the following reaction at $$300 \mathrm{~K}$$. $$\mathrm{NH}_4 \mathrm{NO}_{3(\mathrm{~s})} \long...

What is the work done during oxidation of 4 moles of $$\mathrm{SO}_{2(\mathrm{~g})}$$ to $$\mathrm{SO}_{3(\mathrm{~g})}$$ at $$27^{\circ} \mathrm{C}$$...

Identify the type of system if boiling water is kept in a half filled closed vessel.

What is the value of increase in internal energy when system does $$8 \mathrm{~J}$$ of work on surrounding by supplying $$40 \mathrm{~J}$$ of heat to ...

Which among the following is TRUE for isobaric process?

What is value of PV type of work for following reaction at 1 bar? $$\underset{(200 \mathrm{~mL})}{\mathrm{C}_2 \mathrm{H}_{4(\mathrm{~g})}}+\underset{...

A gas absorbs $$200 \mathrm{~J}$$ heat and expands by $$500 \mathrm{~cm}^3$$ against a constant external pressure $$2 \times 10^5 \mathrm{~N} \mathrm{...

Which among the following pair of properties is intensive?

If $$8.84 \mathrm{~kJ}$$ heat is liberated for formation of $$3 \mathrm{~g}$$ ethane, calculate its $$\triangle_{\mathrm{f}} \mathrm{H}^{\circ}$$....

The difference between $$\Delta \mathrm{H}$$ and $$\Delta \mathrm{U}$$ is usually significant for systems consisting of :

What is change in internal energy when system releases $$8 \mathrm{~kJ}$$ of heat and performs $$660 \mathrm{~J}$$ of work on the surrounding?

Calculate the final volume when 2 moles of an ideal gas expand from $$3 \mathrm{~dm}^3$$ at constant external pressure 1.6 bar and the work done in th...

For $$\mathrm{NaCl}_{(\mathrm{s})}$$ enthalpy of solution is $$4 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ and lattice enthalpy is $$790 \mathrm{~kJ} \mathrm{...

What is the value of $$\Delta H-\Delta U$$ for the following reaction? $$2 \mathrm{C}_{(\mathrm{s})}+3 \mathrm{H}_{2(\mathrm{~g})} \rightarrow \mathrm...

An ideal gas expands by $$1.5 \mathrm{~L}$$ against a constant external pressure of $$2 \mathrm{~atm}$$ at $$298 \mathrm{~K}$$. Calculate the work don...

Which among the following reactions exhibits $$\Delta \mathrm{H}=\Delta \mathrm{U}$$ ?

An ideal gas expands by performing $$200 \mathrm{~J}$$ of work, during this internal energy increases by $$432 \mathrm{~J}$$. What is enthalpy change?...

Calculate the value of $$\Delta G$$ for following reaction at $$300 \mathrm{~K}$$. $$\begin{aligned} & \mathrm{H}_2 \mathrm{O}_{(\mathrm{s})} \longrig...

What is the value of temperature in degree Celsius at absolute zero ?

Calculate the work done when 2 moles of an ideal gas expand from a volume of $$5 \mathrm{~dm}^3$$ to $$7 \times 10^{-3} \mathrm{~m}^3$$ against a cons...

What is the heat of formation of $$\mathrm{HCl}_{(\mathrm{g})}$$ from following equation? $$\mathrm{H}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{g})} \r...

If $$\mathrm{Q}$$ is the heat liberated from the system and $$\mathrm{W}$$ is the work done on the system then first law of thermodynamics can be writ...

For isochoric process, the first law of thermodynamics can be expressed as

When certain volume of gas expands against a constant external pressure of $$2.40 \times 10^5 \mathrm{~Pa}$$ at 300 $$\mathrm{K}$$ to $$2.2 \times 10^...

What is internal energy change when $$62 \mathrm{~J}$$ of work is done on the system and $$128 \mathrm{~J}$$ of heat is transferred to surrounding?...

A gas is allowed to expand against a constant external pressure of 2.5 bar from an initial volume 'x' L to final volume of 4.5 L. If amount of work do...

In a process, a system performs $$238 \mathrm{~J}$$ of work on it's surrounding by absorbing $$54 \mathrm{~J}$$ of heat. What is the change in interna...

When $$\mathrm{x} \mathrm{kJ}$$ heat is provided to a system, work equivalent to $$\mathrm{y} \mathrm{J}$$ is done on it. What is internal energy chan...

What is the constant external pressure of an ideal gas when expanded from $$2 \times 10^{-2} \mathrm{~m}^3$$ to $$3 \times 10^{-2} \mathrm{~m}^3$$, if...

During a process, system absorbs $$710 \mathrm{~J}$$ of heat and increases the internal energy by $$460 \mathrm{~J}$$. What is the work performed by s...

Which among the following is NOT an intensive property?

A system gives out $$\mathrm{x} \mathrm{~J}$$ of heat and does $$\mathrm{y} \mathrm{~J}$$ of work on it's surrounding. What is the internal energy cha...

A system does 394 J of work on surrounding by absorbing 701 J heat. What is the change in internal energy of the system?

Formation of $$\mathrm{NO}_{2(\mathrm{g})}$$ from $$\mathrm{N}_{2(\mathrm{g})}$$ and $$\mathrm{O}_{2(\mathrm{g})}$$ is an endothermic process. Which o...

What is enthalpy of formation of $$\mathrm{NH}_3$$ if bond enthalpies are as $$(\mathrm{N} \equiv \mathrm{N})=941 \mathrm{~kJ},(\mathrm{H}-\mathrm{H})...

What is the difference between $$\Delta H$$ and $$\Delta \mathrm{U}$$ for reaction given below at $$298 \mathrm{~K}$$ ? ($$\mathrm{R}=8.314 \mathrm{JK...

Enthalpy of formation of methane is $$-$$75 kJ/mol. What is the enthalpy change for formation of 24 g of methane?

The expansion of gas having no opposing force is called as

1 mole of an ideal gas expands isothermally and reversibly by decreasing pressure form $$210 \mathrm{~kPa}$$ to $$105 \mathrm{~kPa}$$ at $$300 \mathrm...

When 1 mole of gas is heated at constant volume, the temperature rises form $$273 \mathrm{~K}$$ to $$546 \mathrm{~K}$$. If heat supplied to the gas is...

What is the value of $$\mathrm{\Delta H-\Delta U}$$ for the formation of 2 moles of ammonia from $$\mathrm{H_{2(g)}}$$ and $$\mathrm{N_{2(g)}}$$ ?...

Two moles of an ideal gas are expanded isothermally from $$15 \mathrm{dm}^3$$ to $$20 \mathrm{dm}^3$$. If the amount of work done is $$-6 \mathrm{dm}^...

Find the value of $$-197^\circ$$C temperature in Kelvin.

Which among the following is NOT an extensive property?

A gas is allowed to expand in an insulated container against a constant external pressure of 2.5 atm from $$2.5 \mathrm{~L}$$ to $$4.5 \mathrm{~L}$$, ...

What is the work done when a gas is compressed from 2.5 $$\times$$ 10$$^{-2}$$ m$$^3$$ to 1.3 $$\times$$ 10$$^{-2}$$ m$$^3$$ at constant external pres...

Calculate heat of formation of $$\mathrm{HCl}$$ gas from following reaction. $$\mathrm{H}_{2(\mathrm{~g})}+\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 ...

Calculate difference between $$\Delta \mathrm{H}$$ and $$\Delta \mathrm{U}$$ for following reaction at $$25^{\circ} \mathrm{C}$$ ? $$\mathrm{C}_2 \mat...

The change in internal energy of a system depends upon

Which of the following reactions shows work of compression?

Calculate change in enthalpy when 39 g acetylene is completely burnt with oxygen and enthalpy of combustion of acetylene is $$-$$1300 kJ/mol. (At. mas...

An ideal gas on isothermal reversible compression from 10L to 5L performs 1730J of work at 300 K. Calculate number of moles of gas involved in compres...

What is standard $N \equiv N$ bond enthalpy from following reaction, $$\begin{aligned} & \mathrm{N}_2(g)+3 \mathrm{H}_2(g) \longrightarrow 2 \mathrm{N...

For the reaction, $$\mathrm{N}_2(g)+3 \mathrm{H}_2(g) \longrightarrow 2 \mathrm{NH}_3(g) ; \Delta H$$ is equal to

When 6.0 g of graphite reacts with dihydrogen to give methane gas, 37.4 kJ of heat is liberated. What is standard enthalpy of formation of $\mathrm{CH...

Work done when 2 mole of an ideal gas is compressed from a volume of $$5 \mathrm{~m}^3$$ to $$2.5 \mathrm{~m}^3$$ at 300 K, under a pressure of 100 kp...

If entropy of a solid is greater than zero, at $$T=0$$, it is called

A sample of gas absorbs $$4000 \mathrm{~kJ}$$ of heat and surrounding does $$2000 \mathrm{~J}$$ of work on sample. What is the value of $$\Delta U$$ ?...

If $$38.55 \mathrm{~kJ}$$ of heat is absorbed, when 6.0 of $$\mathrm{O}_2$$ react $$\mathrm{CIF}$$ according to reaction. $$2 \mathrm{CIF}(g)+\mathrm{...

An ideal gas expands isothermally and reversibly from $$10 \mathrm{~m}^3$$ to $$20 \mathrm{~m}^3$$ at $$300 \mathrm{~K}$$, performing $$5.187 \mathrm{...

"The mass and energy both are conserved in an isolated system", is the statement of

The temperature of $32^{\circ} \mathrm{C}$ is equivalent to

A gas performs 0.320 kJ work on surrounding and absorbs 120 J of heat from the surrounding. Hence, change in internal energy is

Based on first law of thermodynamics which of the following is correct

Identify the equation in which change in enthalpy is equal to change in internal energy

Two moles of an ideal gas is expanded isothermally and reversibly at 300 K from 1 L to 10 L . The enthalpy change in kJ is

$$\begin{aligned} & \text { If } \mathrm{C}(s)+\mathrm{O}_2(g) \rightarrow \mathrm{CO}_2(g), \Delta H=-X \\ & \mathrm{CO}(g)+\frac{1}{2} \mathrm{O}_2(...

Three moles of an ideal gas are expanded isothermally from a volume of $300 \mathrm{~cm}^3$ to 2.5 L at 300 K against a pressure of 1.9 atm . The work...

Calculate the difference between heat of combustion of carbon monoxide gas at constant pressure and at constant volume at $27^{\circ} \mathrm{C} ?\lef...

For a process, entropy change of a system is expressed as