Which of the following aqueous solutions exhibits lowest freezing point depression assuming complete dissociation?

Calculate the temperature of 0.05 M sucrose solution in Kelvin if the osmotic pressure of the solution is 1.5 atm .

$$ \left[\mathrm{R}=0.0821 \mathrm{dm}^3 \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right] $$

Calculate molality of the solution containing nonvolatile solute if boiling point elevation of the solution is 0.2 K

$$ \left[\mathrm{K}_{\mathrm{b}}=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}\right] $$

Find the expected value of $\Delta \mathrm{T}_{\mathrm{b}}$ for $1 \mathrm{~m} \mathrm{AlCl}{ }_3$ solution in water if solution of nonelectrolyte of same concentration has $\Delta \mathrm{T}_{\mathrm{b}}$ value ' $x$ ' K .