MHT CET 2025 23rd April Evening Shift | Electrochemistry Question 1 | Chemistry

${ }^{\ominus} \mathrm{Ni}_{(s)}|\stackrel{+2}{\mathrm{~N}} \mathrm{i}(0.01 \mathrm{M}) \| \stackrel{+}{\mathrm{Ag}}(0.01 \mathrm{M})| \stackrel{\oplus}{\mathrm{Ag}_{(s)}}$

less than $\mathrm{E}_{\text {cell }}^{\circ}$ by 0.0592 V

greater than $\mathrm{E}_{\text {cell }}^{\circ}$ by 0.0592 V

less than $\mathrm{E}_{\text {cell }}^{\circ}$ by 0.0296 V

greater than $\mathrm{E}_{\text {cell }}^{\circ}$ by 0.0296 V

MHT CET 2025 23rd April Evening Shift

MCQ (Single Correct Answer)

-0

The standard emf for cell, ${ }^{\ominus} \mathrm{Cd}_{(\mathrm{s})}\left|{ }^{+2} \mathrm{Cd}(1 \mathrm{M}) \| \stackrel{+2}{\mathrm{Cu}}(1 \mathrm{M})\right| \mathrm{Cu}_{(\mathrm{s})}{ }^{\oplus}$ is 0.74 V .

If concentration of $\mathrm{Cd}_{(\mathrm{aq})}^{+2}$ and $\mathrm{Cu}_{(\mathrm{aq})}^{+2}$ decreases by 10 times at 298 K . Calculate emf of cell.

+0.074 V

+0.850 V

+0.680 V

+0.740 V

MHT CET 2025 23rd April Evening Shift

MCQ (Single Correct Answer)

-0

A hypothetical galvanic cell is ${ }^{\ominus} \mathrm{A}_{(\mathrm{s})} \mid \stackrel{+}{\mathrm{A}}(1 \mathrm{M})\|\stackrel{+2}{\mathrm{~B}}(1 \mathrm{M})\| \stackrel{\oplus}{\mathrm{B}}_{(\mathrm{s})}$ and emf of cell is positive. What is the possible cell reaction?

$\quad \mathrm{A}_{(\mathrm{s})}+\stackrel{+B}{B}_{(\mathrm{aq})} \longrightarrow \stackrel{+1}{A}_{(\mathrm{aq})}+\mathrm{B}_{(\mathrm{s})}$

$\quad 2 \mathrm{~A}_{(\mathrm{s})}+\stackrel{+}{\mathrm{B}}_{(\mathrm{aq})} \longrightarrow 2 \stackrel{+1}{\mathrm{~A}}_{(\mathrm{aq})}^{+}+\mathrm{B}_{(\mathrm{s})}$

$\quad \mathrm{A}_{(\mathrm{s})}+2 \stackrel{+2 B}{(\mathrm{aq})}^{+2} \xrightarrow{+1} \mathrm{~A}_{(\mathrm{aq})}+2 \mathrm{~B}_{(\mathrm{s})}$

$\quad 2 \stackrel{+}{\mathrm{A}}_{(\mathrm{aq})}+\mathrm{B}_{(\mathrm{s})} \longrightarrow 2 \mathrm{~A}_{(\mathrm{s})}+\stackrel{+2}{\mathrm{~B}}_{(\mathrm{aq})}$

MHT CET 2025 23rd April Morning Shift

MCQ (Single Correct Answer)

-0

Consider galvanic cell, ${ }^{\ominus} \mathrm{A}_{(\mathrm{s})}\left|\mathrm{A}_{(\mathrm{aq})}^{+2}\right|\left|\mathrm{B}_{(\mathrm{aq})}^{+}\right| \mathrm{B}_{(\mathrm{s})}^{\oplus}$

if emf of cell is positive, identify a correct cell reaction from following.

$\quad \mathrm{A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+2} \longrightarrow \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})}$

$\quad \mathrm{A}_{(\mathrm{s})}+2 \mathrm{~B}_{(\mathrm{aq})}^{+} \longrightarrow \mathrm{A}_{(\mathrm{aq})}^{+2}+2 \mathrm{~B}_{(\mathrm{s})}$

$\quad 2 \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})} \longrightarrow 2 \mathrm{~A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+}$

$\quad 2 \mathrm{~A}_{(\mathrm{s})}+\mathrm{B}_{(\mathrm{aq})}^{+} \longrightarrow 2 \mathrm{~A}_{(\mathrm{aq})}^{+2}+\mathrm{B}_{(\mathrm{s})}$

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